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US 5,106,931 AGranted
Copolymerization of ethylene and cycloolefin isomerized from endo-form to exo-form
AssigneeMitsui Petrochemical Industries, Ltd.
InventorsToshihiro Sagane, Hideaki Yamaguchi, Shuji Minami, Akira Mizuno, Hiroo Wamura
Life of this patent
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Abstract
This invention is to provide a novel process for the isomerization of a cycloolefin having an endo form to a cycloolefin having an exo form. The resulting isomer mixture has a novel composition, and a random copolymer produced from the above compositionally novel isomer mixture and ethylene has an excellent heat resistance and mechanical strength.
Claims8
A cycloolefinic random copolymer:
- (1) which is a copolymer formed from ethylene and an isomer mixture of up to 80 mol % of a cycloolefin having an endo form with at least 20 mol % of the cycloolefin having an exo form, the cycloolefin having the following formula (I) ##STR34## wherein R.sup.1 to R.sup.14 are independently a hydrogen atom, a halogen atom or a hydrocarbon group, R.sup.15 to R.sup.18 are independently a hydrogen atom, a halogen atom or a hydrocarbon group, or R.sup.15 or R.sup.16 and R.sup.17 or R.sup.18 may be bonded to each other to form a monocyclic or polycyclic group, or R.sup.15 and R.sup.16 or R.sup.17 and R.sup.18 may together form an alkylidene group only when n is 1, n is 0 or 1, and m is 0 or a positive integer, provided that m and n cannot be simultaneously zero,
- (2) which has, based on a total of polymer units derived from the cycloolefin and polymer units derived from the ethylene, 10 to 90 mol % of the polymer units derived from the cycloolefin and 90 to 10 mol % of the polymer units derived from the ethylene,
- (3) wherein the polymer units derived from the cycloolefin have the following formula (II) ##STR35## wherein R.sup.1 to R.sup.18, n and m are as defined as above, and (4) which has an intrinsic viscosity (.eta.), measured in decahydronaphthalene at 135.degree. C., of 0.05 to 10 dl/g.
A random copolymer:
- (1) which is formed from ethylene and an isomer mixture of up to 80 mol % of a cycloolefin having an endo form with at least 20 mol % of the cycloolefin having an exo form, the cycloolefin having the following formula (I-B) ##STR38## wherein R.sup.1 to R.sup.10 are independently a hydrogen atom, a halogen atom or a hydrocarbon group, R.sup.15 to R.sup.18 are independently a hydrogen atom, a halogen atom or a hydrocarbon group, or R.sup.15 or R.sup.16 and R.sup.17 or R.sup.18 may be bonded to each other to form a monocyclic or polycyclic group, or R.sup.15 and R.sup.16 or R.sup.17 and R.sup.18 may together form an alkylidene group,
- (2) which has, based on a total of polymer units derived from the cycloolefin and polymer units derived from the ethylene, 10 to 90 mol % of the polymer units derived from the cycloolefin and 90 to 10 mol % of the polymer units derived from the ethylene,
- (3) wherein the polymer units derived from the cycloolefin have the following formula (II-B) ##STR39## wherein R.sup.1 to R.sup.10 and R.sup.15 to R.sup.18 are as defined above, and
- (4) which has an intrinsic viscosity (.eta.), measured in decahydronaphthalene at 135.degree. C., of 0.05 to 10 dl/g.
1 more element
Dependencies are inferred from the claim text.