Process for production of chlorinated ethylene-propylene copolymers
AssigneeShowa Denko K.K.
InventorsNaotoshi Watanabe, Tsuyoshi Masukawa, Kenji Ozaki, Noboru Moriwaki
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AssigneeShowa Denko K.K.
InventorsNaotoshi Watanabe, Tsuyoshi Masukawa, Kenji Ozaki, Noboru Moriwaki
Estimating the term…
A chlorinated ethylene-propylene copolymer having a chlorine content of 20 to 45% by weight and a Mooney viscosity (ML.sub.1+4, 100.degree. C.) of 10 to 150 is produced by chlorinating in two or three stages, by contact with chlorine gas in an aqueous suspension, an ethylene-propylene copolymer having a propylene content of 15 to 40% by weight, a melt flow index of 0.01 to 5.0 g/10 minutes, a melting peak as measured by differential scan calorimeter (DSC) of 80.degree. C. or more, a crystallinity as measured by X-rays of 3% or more, an index M.sub.W /M.sub.N of the distribution of molecular weight, determined by gel permeation chromatography (GPC), of greater than 4, and a Mooney visocisty (ML.sub.1+4, 100.degree. C.) of 10 to 180. A vulcanizable composition having superior physical properties may be obtained by formulating with (A) the chlorinated ethylene-propylene copolymer, (B) a thiourea compound, (C) sulfur and/or a sulfur donor, (D) a metal compound, and furthur, if necessary, (E) a dicarbamate or (F) a mercaptotriadizine compound. Furthur, a cross-linkable composition having superior physical properties may be obtained by formulating (A) the chlorinated ethylene-propylene copolymer with (G) an organic peroxide.
A method for producing a chlorinated ethylene-propylene copolymer comprising contacting a starting ethylene-propylene copolymer, wherein the propylene content is 20 to 38% by weight, the melt flow index is 0.01 to 5.0 g/10 minutes, the melting peak as measured by differential scan calorimetry (DSC) is 80.degree. C. or more, the crystallinity as measured by X-rays is 3 to 45%, the index M.sub.W /M.sub.N of the distribution of molecular weight, determined by gel permeation chromatography (GPC), is greater than 4, and the Mooney viscosity (ML.sub.1+4, 100.degree. C.) is 10 to 180, with chlorine gas in an aqueous suspension, to produce a chlorinated ethylene-propylene copolymer having a chlorine content of 20 to 45% by weight and a Mooney viscosity (ML.sub.1+4, 100.degree. C.) of 10 to 150, wherein
A method for producing a chlorinated ethylene-propylene copolymer comprising contacting a starting ethylene-propylene copolymer, wherein the propylene content is 20 to 38% by weight, the melt flow index is 0.01 is 5.0 g/10 minutes, the melting peak as measured by differential scan calorimetry (DSC) is 80.degree. C. or more, the crystallinity as measured by X-rays is 3% to 6.2%, the index M.sub.W /M.sub.N of the distribution of molecular weight, determined by gel permeation chromatography (GPC), is greater than 4 but not more than 8, and the Mooney viscosity (ML.sub.1+4, 100.degree. C.) is 10 to 150, with chlorine gas in an aqueous suspension, to produce a chlorinated ethylene-propylene copolymer having a chlorine content of 20 to 45% by weight, a Mooney viscosity (ML.sub.1+4, 100.degree. C.) of 10 to 100 and a melt flow index of 1 to 100 g.10 minutes, wherein
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