Polypropylene wax and process for the production thereof
AssigneeHoechst Aktiengesellschaft
InventorsAndreas Winter, Volker Dolle, Jurgen Rohrmann, Martin Antberg, Ludwig Bohm, Walter Spaleck
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AssigneeHoechst Aktiengesellschaft
InventorsAndreas Winter, Volker Dolle, Jurgen Rohrmann, Martin Antberg, Ludwig Bohm, Walter Spaleck
Estimating the term…
Polyolefin waxes are obtained in high yield by copolymerizing propylene with small amounts of other olefins in the presence of a catalyst composed of a metallocene of the formula I: ##STR1## and an alumoxane. The waxes are produced as compact, spherical particles having a narrow particle size distribution and high apparent density. In addition, the physical data of these waxes such as, for example, hardness, melting point, melt viscosity etc., are variable within wide limits. The polymer chains are noteworthy for a homogeneous and uniform structure, the comonomer units being predominantly arranged individually between polypropylene blocks.
A polypropylene wax comprised of 80 to 99.75% by weight, based on the total polymer, of propylene units and 0.25 to 20% by weight, based on the total polymer, of units which are derived from ethylene or an olefin containing not less than 4 carbon atoms of the formula R.sup.15 --CH.dbd.CH--R.sup.16, in which R.sup.15 and R.sup.16 are identical or different and are a hydrogen atom or an alkyl radical containing 1 to 28 carbon atoms or R.sup.15 and R.sup.16 form a ring containing 4 to 28 carbon atoms with the carbon atoms joining them, which polypropylene wax has a molar mass M.sub.w of 1,000 to 50,000 g/mol, a polydispersity M.sub.w /M.sub.n of 1.8 to 5.0, a viscosity number of 2 to 60 cm.sup.3 /g, a melting point of 50.degree. to 150.degree. C., an enthalpy of fusion .DELTA.H of less than 100 J/g, a dropping point of 60.degree. to 160.degree. C., a melt viscosity at 170.degree. C. of 100 to 20,000 mPa.s and a regular distribution of the comonomer units in the polymer chain, the mean block length n being less than 1.25.
Dependencies are inferred from the claim text.