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US 5,077,335 AGranted
Optically clear silicone compositions
AssigneeBayer Aktiengesellschaft
InventorsPeter Schwabe, Reiner Voigt, Ottfried Schlak, Otto-Christian Geyer
Life of this patent
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Abstract
The present invention relates to optically clear polysiloxane-based compositions which are employed, in particular, for the production of contact optical articles such as contact lenses, scleral lenses and intraocular lenses.
Claims9
In an optically clear silicone composition which can be cured to an elastomer comprising
- a) an organopolysiloxane with two or more vinyl groups in the molecule,
- b) optionally an organopolysiloxane without reactive groups,
- c) an organopolysiloxane with two or more SiH groups in the molecule,
- d) a catalyst containing Pt metal or Pt metal complexes, and
- e) an inhibitor,
- wherein the improvement comprises
- the silicone composition additionally contains a low molecular weight tetrafunctional SiO.sub.4/2 --and monofunctional R.sub.3 SiO.sub.1/2 --containing resin which contains vinyl and ethoxy groups and is homogeneously soluble in a) and which resin, firstly, has a vinyl group content of 0.5-8 mmol/g, secondly, consists of SiO.sub.4/2, RO.sub.1/2 and R.sub.3 SiO.sub.1/2 units, where R represents a methyl, vinyl, phenyl or ethyl group, and has an ethoxy group content of less than 4 mmol/g and, thirdly, is present in the silicone composition to the extent of 1-10% by weight,
- the catalyst content--calculated as metal--is less than 5 ppm based on the total mixture,
- the SiH group content is from 0.05 to 0.8 mmol/g based on the total mixture,
- the inhibitor is an organopolysiloxane containing 0.5 to 11.6 mmol vinyl/g,
- the specific gravity of the curable silicone composition is less than 1.0, and
- the silicone composition optionally additionally contains branched saturated hydrocarbons with 15-50 C atoms.
9 more elements
Dependencies are inferred from the claim text.