Production of high viscosity index lubricating oil stock
AssigneeMobil Oil Corporation
InventorsThomas F. Degnan, Ernest W. Valyocsik
Life of this patent
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Abstract
Waxy hydrocarbon oils, e.g., of petroleum origin, are catalytically dewaxed to produce high viscosity index lubricating oil stocks utilizing as catalyst acidic zeolite ZSM-48.
Claims11
A process for preparing a porous silico-crystal characterized by an X-ray diffraction pattern whose values are set forth in Table 1 of the specification which comprises:
- preparing a reaction mixture containing a source of silica, a source of trivalent metal oxide corresponding to the formula Me.sub.2 O.sub.3, an alkali metal oxide, an organic linear diquaternary ammonium compound, and water, and having a composition in terms of mole ratios falling within the following ranges:
- SiO.sub.2 Me.sub.2 O.sub.3 =100 to infinity
- H.sub.2 O/SiO.sub.2 =5 to 400
- OH/SiO.sub.2 =) to 2.0
- M.sup.+ SiO.sub.2 =0 to 2.0
- R/SiO.sub.2 =0.005 to 2.0
- wherein Me is a trivalent metal, M is an alkali metal, and R is an organic linear diquaternary ammonium compound, said organic linear diquaternary ammonium compound corresponding to the formula
- [(R').sub.3 N.sup.+ (Z).sub.m N.sup.+ (R').sub.3 ](X.sup.-).sub.2
- wherein R' is alkyl of from 1 to 20 carbon atoms, Z is a bridging member selected from the group consisting of alkyl of from 1 to 20 carbon atoms, and m is 5, 6, 8, 9 or 10.
A composition comprising a substantially pure silico-crystal ZSM-48 prepared with an organic linear diquaternary ammonium compound as the directing agent and having a silica/alumina mole ratio of from 100 to 250.
A silico-crystal ZSM-48 prepared with an organic linear diquaternary ammonium compound as the directing agent and having a platelet crystal morphology.
A silico-crystal ZSM-48 prepared with an organic linear diquaternary ammonium compound as the directing agent and having an irregular crystal morphology.
Dependencies are inferred from the claim text.