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US 5,055,438 AGranted
Olefin polymerization catalysts
AssigneeExxon Chemical Patents Inc.
InventorJo Ann M. Canich
Life of this patent
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Abstract
The invention is a polymerization catalyst system including an alumoxane and a Group IV B metallocene having a heteroatom ligand. The catalyst system can be employed to polymerize olefins to produce a high molecular weight polymer.
Claims7
A catalyst system comprising:
- (A) a Group IV B transition metal component of the formula:
- ##STR5## wherein M is Zr, Hf or Ti;
- (C.sub.5 H.sub.5-y-x R.sub.x) is a cyclopentadienyl ring which is substituted wit from zero to five groups R, "x" is 0, 1, 2, 3, 4 or 5 denoting the degree of substitution, and each R is, independently, a radical selected from a group consisting of C.sub.1 -C.sub.20 hydrocarbyl radicals, C.sub.1 -C.sub.20 substituted hydrocarbyl radicals wherein one or more hydrogen atoms are replaced by a halogen atom, C.sub.1 -C.sub.20 hydrocarbyl-substituted metalloid radicals wherein the metalloid is selected from the Group IV A of the Periodic Table of Elements and halogen radicals or (C.sub.5 H.sub.5-y-x R.sub.x) is a cyclopentadienyl ring in which two adjacent R-groups are joined forming C.sub.4 -C.sub.20 ring to give a saturated or unsaturated polycyclic cyclopentadienyl ligand;
- (JR'.sub.z-l-y) is a heteroatom ligand in which J is an element with a coordination number of three from Group V A or an element with a coordination number of two from Group VI A of the Periodic Table of Elements, each R' is, independently a radical selected from a group consisting of C.sub.1 -C.sub.20 hydrocarbyl radicals, substituted C.sub.1 -C.sub.20 hydrocarbyl radicals wherein one or more hydrogen atoms is replaced by a halogen atom, and "z" is the coordination number of the element J;
- each Q is, independently any univalent anionic ligand or two Q's are a divalent anionic chelating agent;
- "y" is 0 or 1 when w is greater than 0;
- y is 1 when w is 0, when "y" is 1, T is a covalent bridging group containing a Group IV A or V A element;
- L is a Lewis base where "w" denotes a number from 0 to 3;
- and
- (B) an alumoxane.
7 more elements
Dependencies are inferred from the claim text.