Process for producing a high-temperature superconductor and also shaped bodies composed thereof
AssigneeHoechst Aktiengesellschaft
InventorsJoachim Bock, Eberhard Preisler
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AssigneeHoechst Aktiengesellschaft
InventorsJoachim Bock, Eberhard Preisler
Estimating the term…
To produce a high-temperature superconductor of the composition Bi.sub.2 (Sr,Ca).sub.3 Cu.sub.2 O.sub.8+x having a strontium to calcium ratio of 5:1 to 2:1 and a value of x between 0 and 2, the oxides and/or carbonates of bismuth, strontium, calcium and copper are vigorously mixed in a stoichiometric ratio. The mixture is heated at temperatures of 870.degree. to 1100.degree. C. until a homogeneous melt is obtained. The melt is poured into molds and allowed to solidify in them. The cast bodies removed from the molds are annealed for 6 to 30 hours at 780.degree. to 850.degree. C. Finally, the annealed cast bodies are treated for at least 6 hours at temperatures of 600.degree. to 820.degree. C. in an oxygen atmosphere. The cast bodies can be converted into shaped bodies of the desired sizes by mechanical processes before they are annealed. The shape and size of the shaped bodies may also be determined by the shape and dimensioning of the molds used in producing the cast bodies.
A process for producing a high-temperature superconductor of the composition Bi.sub.2 (Sr,Ca).sub.3 Cu.sub.2 O.sub.8+z, the ratio of strontium to calcium being (5 to 2) :
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