Disperson polymers which contain urea groups and are based on ethylenically unsaturated monomers, process for their preparation and their use
AssigneeHoechst Aktiengesellschaft
InventorsKarl J. Rauterkus, Hans-Ullrich Huth, Karl-Hans Angelmayer
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Abstract
Dispersion polymers based on ethylenically unsaturated monomers, the polymers containing at least 1% by weight of specific monomer units of ethylenically unsaturated urea derivatives (see formula I), process for their preparation particularly by free-radical initiated emulsion, suspension or bead polymerization or copolymerization and their use as coating compositions, preferably in the form of aqueous dispersions, particularly as corrosion inhibiting metal coating compounds, moreover as adhesives, molded plastics and as binders, thickeners and auxiliaries in industrial chemical compositions.
Claims9
A polymer based on ethylenically unsaturated monomers, which contains monomer units of urea derivatives with .alpha.,.beta.-ethylenically unsaturated carboxyl or carboxamide radicals and has been produced by solution, emulsion, suspension or bead polymerization or copolymerization, or a solution or aqueous dispersion of this polymer, wherein the polymer contains at least 1% by weight of monomer units of ethylenically unsaturated urea derivatives of the formula ##STR6## the radicals R.sup.1 to R.sup.5 and Z have the following meaning in formula I:
- R.sup.1, R.sup.2, R.sup.3, which may be identical or different,
- =H or CH.sub.3,
- Z= ##STR7## R.sup.7 =H or CH.sub.3 and m, p=in each case at least the number 1, R.sup.4, R.sup.5, which may be identical or different, =H, an optionally substituted (C.sub.1 -C.sub.30)-alkyl, an optionally substituted --(C.sub.k H.sub.2k)--OH with k=1 to 8, an optionally substituted (C.sub.6 -C.sub.10)-aryl, an optionally substituted (C.sub.7 -C.sub.30)-aralkyl, an optionally substituted (C.sub.5 -C.sub.8)-cycloalkyl, an optionally substituted 5- to 7-membered heterocycle or an optionally substituted heterocycle formed from R.sup.4 and R.sup.5 jointly with the nitrogen atom.
Dependencies are inferred from the claim text.