Metal container coating compositions comprising an acrylic polymer latex, melamine formaldehyde resin and an phenol formaldehyde resin
AssigneeThe Dexter Corporation
InventorHarold F. Cole
Life of this patent
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Abstract
Water borne, water dilutable metal can coating compositions containing (A) an acrylic polymer latex including an alkyloxymethylacrylamide or -methacrylamide monomer, (B) a melamine/formaldehyde resin, (C) an alkanolamine treated phenol/formaldehyde resin, (D) a lubricant and (E) a defoamer in a water or water/organic solvent mixture are provided. These compositions cure between 15 seconds and 1 minute at moderate can coating cure temperature and permit faster can coating machine speeds on Rutherford can coating machines.
Claims8
A water borne, water dilutable coating composition for wash coat or varnish coat application to metal containers intended for the packaging of beverages and food products comprising a mixture of
- (A) from about 10 to about 90 percent by weight of an acrylic polymer latex containing an acrylamide or methacrylamide polymer component formed from the following monomeric ingredients:
- ______________________________________ INGREDIENT PERCENT BY WT. ______________________________________ (1) Styrene 3-10 percent (2) ethyl acrylate 0-20 percent (3) butyl acrylate 0-20 percent (4) methyl methacrylate 5-8 percent (5) methacrylic acid 3-7 percent (6) C.sub.1 to C.sub.6 -alkyl 0.5-3 percent oxymethyl- acrylamide or methacrylamide ______________________________________
- based upon the total materials added to the acrylic polymer latex component, in a liquid medium selected from the group consisting of water and a mixture of water with an organic liquid solvent to provide from about 30 to 35 percent by weight of nonvolatile materials in said polymer latex component,
- (B) from about 1 to about 50 percent by weight of the total solids in the composition of a melamine/formaldehyde resin,
- (C) from 0.5 to 50 percent by weight of the total solids in the composition of a base treated phenol/formaldehyde source resin composition, which phenol/formaldehyde resin has a viscosity of 20 seconds maximum using a No. 4 Ford cup viscosity test method,
- (D) from about 0.1 to about 10 percent by weight of a coating polymer compatible lubricant uniformly dispersible in the total coating composition,
- (E) from about 0.1 percent to about 5 percent by weight of the total solids in the composition of a defoamer material selected from the group consisting of (1) an alkyl-branched alkynyl diol having from 10 to 20 carbon atoms and (2) aliphatic mineral spirits having C.sub.1 to C.sub.12 -isaparaffinic hydrocarbons,
- said can coating composition containing therein sufficient liquid selected from the group consisting of water and a water/organic liquid solvent mixture to maintain the components (A) to (E) dispersible therein.
Dependencies are inferred from the claim text.