Process for the gas-phase polymerization of olefins in a fluidized-bed reactor
AssigneeBP Chemicals Limited
InventorsJean-Claude Chinh, Andre Dumain
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AssigneeBP Chemicals Limited
InventorsJean-Claude Chinh, Andre Dumain
Estimating the term…
The present invention relates to a process and apparatus for the gas-phase polymerization of olefins in a fluidized-bed reactor maintained at a temperature T1. A gaseous reaction mixture comprising the olefins to be polymerized passes through the reactor and is recycled to the reactor by means of a recycling line comprising successively a first heat transfer means, a compressor and a second heat transfer means. The present invention consists in introducing a readily volatile liquid hydrocarbon into the inlet of the first heat transfer means or into the recycling line, upstream and in the vicinity of the first heat transfer means. The first heat transfer means cools the gaseous reaction mixture to a temperature T2, below T1, while volatilizing the readily volatile hydrocarbon and without condensing a constituent of the gaseous reaction mixture. The second heat transfer means cools the gaseous reaction mixture to a temperature T3, below T2, for maintaining the fluidized-bed at the desired temperature T1.
A process for the gas phase polymerisation of one or more olefins containing from 2 to 10 carbon atoms, in a fluidised-bed reactor in the presence of a catalyst system of the Ziegler-Natta type or a catalyst based on chromium oxide, introduced into the reactor continuously or intermittently, the polymer being produced in the fluidised bed at a temperature T1 which is below the melting point of the polymer and drawn off from the reactor continuously or intermittently, the solid particles of the bed being kept in the fluidised state by means of a gaseous reaction mixture comprising the olefin or olefins to be polymerised, which gaseous reaction mixture passes through the reactor in a rising stream, leaves through the top of the reactor with fine particles entrained and directly returns into the bottom part of the reactor by means of a gas recycling line external to the reactor which line includes in succession in the direction of flow of the gaseous reaction mixture, a first heat transfer cooling means, a compressor, and a second heat transfer cooling means, characterised in that:
Dependencies are inferred from the claim text.