Preparation of highly oxidized RBa.sub.2 Cu.sub.4 O.sub.8 superconductors
AssigneeThe Regents of the University of California
InventorDonald E. Morris
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Abstract
Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known syntheses in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed. The compounds and structures thus formed are substantially nonsusceptible to variations in their oxygen content when subjected to changing temperatures, thereby forming a temperature-stable substantially single phase crystal.
Claims14
A process for producing a superconducting material, said process comprising:
- (a) forming a composition by admixing (i) a compound of a metal selected from the group consisting of yttrium and rare earth metals with (ii) a compound of barium and (iii) a compound of copper, said compounds selected from the group consisting of oxides, nitrates and carbonates thereof, in relative amounts such that the atomic ratio of said metal to barium to copper in said composition is approximately 1:2:4;
- (b) heating said composition in an oxygen-containing atmosphere having an oxidizing potential greater than 50% molecular oxygen at a pressure of at least 30 atmospheres to a temperature and for a length of time sufficient to effect interdiffusion of said compounds and the formation of a substantially single phase crystalline or polycrystalline lattice structure having approximately the empirical formula RBa.sub.2 Cu.sub.4 O.sub.8 where R is said metal of compound (i), which lattice structure is temperature stable at temperatures below about 750.degree. C.
A process in accordance with claim in which said oxygen-containing atmosphere of step (b) is at least about 50% molecular oxygen.
Dependencies are inferred from the claim text.