A centrifugal contactor comprising housing means having inner wall portions defining an elongated vertically extending cylindrical cavity therein, elongated cylindrical rotor means having openings therein at an upper end and at a lower end thereof disposed in said cavity and having outer vertical wall portions thereon radially inwardly spaced from said inner wall portions of the housing means for defining therewith a vertically oriented annular liquid mixing volume between said inner wall portions and said outer vertical wall portions, two circumferentially spaced apart and tangentially oriented inlet passageway means penetrating said housing means and in registry with said annular mixing volume at a location intermediate the upper and lower ends of said rotor means for introducing liquids into said annular mixing volume for subsequent reception in said rotor means through the opening in the lower end thereof, and stationary vane means carried by said housing means on said inner wall portions at locations vertically spaced from said inlet means and projecting radially inwardly into said annular mixing volume to a location adjacent to said outer vertical wall portions of said rotor means with said vane means being oriented in said annular mixing volume for urging liquid toward said inlet passageway means when said rotor means is rotated and the liquids are in said annular volume.