Argon purification
AssigneeLinde Aktiengesellschaft
InventorsWilhelm Rohde, Horst Corduan
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Abstract
A process and apparatus for air separation by low temperature rectification are described in which argon is obtained exclusively by rectification. A crude argon column (24) is equipped with at least 150 theoretical plates in the form of low pressure drop packing so that, in it, a substantially complete separation of the oxygen is possible, e.g., less than about 10 ppm, preferably less than 1 ppm oxygen.
Claims6
In a process for air separation by low temperature rectification of air, in which air is compressed, prepurified, cooled, fed to a double rectification column comprising a high pressure column having a top and a bottom, said top being in heat exchange relationship with a low pressure column, and separated into an oxygen-rich and a nitrogen-rich fraction, and from the low pressure column of the rectification, an oxygen fraction enriched with argon is removed and, in a crude argon rectification, is separated into crude argon and a higher boiling residual fraction, the improvement which comprises conducting the crude argon rectification in a column having a head condenser, at least 150 theoretical plates, and provided with low pressure drop structured packings or fillings;
- and cooling the head condenser with liquid from the bottom of the high pressure column, said crude argon rectification resulting in a sufficient separation of oxygen to eliminate any use of a deoxo unit to remove oxygen from the resultant argon.
Dependencies are inferred from the claim text.