Process for removing the nitrite and/or nitrate content in water
AssigneeUmweltschutztechnologie mbH GUTEC: Gesellschaft zur Entwicklung von
InventorsKlaus-Dieter Vorlop, Thomas Tacke, Michael Sell, Gunther Strauss
Life of this patent
Estimating the term…
Abstract
A continuously performable process for the removal or reduction of the nite and/or nitrate content of nitrite-polluted and/or nitrate-polluted water with the selective formation of nitrogen by catalytic hydrogenation. Catalysts suitable for carrying out such a process are also described.
Claims37
A continuously performable process for decreasing the nitrite or nitrate content of nitrite-polluted or nitrate-polluted water with the selective formation of nitrogen, comprising the steps of introducing hydrogen gas into the nitrite or nitrate-polluted water, and contacting the resulting hydrogen-loaded water with a metal catalyst formed of a porous inorganic carrier impregnated with a metal component selected from the group consisting of palladium, rhodium, mixtures of palladium and rhodium, and mixtures of palladium and a metal of the copper group, wherein said inorganic carrier has at least one of the following characteristics (a), (b) and (c):
- (a) a bimodal pore radius distribution with a proportion of at least 20%, relative to the overall pore volume, of macropores having a minimum radius of 2,000 .ANG.;
- (b) a non-homogenous distribution of the metal with a concentration in the surface area or
- (c) is a powder, and
- wherein for treating water polluted only with nitrite, a catalyst is used in which the metal component is selected from the group consisting of palladium, rhodium and mixtures thereof, and wherein for treating water also polluted with nitrate, a catalyst is used in which the metal component is selected from the group consisting of mixtures of palladium and a metal of the copper group, rhodium, and mixtures of rhodium and palladium, or wherein a mixture is used of a catalyst in which the metal component comprises palladium and a metal of the copper group, and of a catalyst in which the metal component consists solely of palladium, and wherein the pH value of the water is maintained not higher than pH 8.
Dependencies are inferred from the claim text.