Bisdiazonium salts of 4,4'-diamino-3,3'-dialkoxybiphenyls and a process for their preparation
AssigneeHoechst Aktiengesellschaft
InventorsHasso Hertel, Klaus Hunger, Heinrich Frolich
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AssigneeHoechst Aktiengesellschaft
InventorsHasso Hertel, Klaus Hunger, Heinrich Frolich
Estimating the term…
Bisdiazonium salts of the formula (1) ##STR1## in which R denotes a linear or branched alkyl or alkoxyalkyl radical having 3-5 carbon atoms and X.sup.- represents the radical of a strong acid or of a zinc chloride double salt, and a process for their preparation by diazotizing a 4,4'-diamino-3,3'-dialkoxybiphenyl of the formula (2) ##STR2## in which R has the meaning mentioned, in an aqueous, strong, non-oxidizing inorganic or organic acid at temperatures from about -10.degree. C. to about +40.degree. C. by means of an alkali metal nitrite, and precipitating the resulting bisdiazonium salts by adding an alkali metal chloride, bisulfate, monosulfonate of 1,5-naphthalenedisulfonic acid or tetrafluoroborate or zinc chloride. These salts are useful in dyeing and printing textile fiber materials by the methods of the ice color technique, using suitable coupling components; they are also useful for preparing photographic tracings by the methods of reprography.
A bis-diazonium salt of the formula ##STR6## in which R denotes linear or branched alkyl or alkoxyalkyl having a total of 3-5 carbon atoms and X.crclbar. represents HSO.sub.3.sup.-, BF.sub.4.sup.- or .sup.-.
A bisdiazonium salt of the formula ##STR7## in which R denotes propyl, butyl, 2-methoxyethoxy or 2-ethoxyethoxy, and X.sup.31 denotes BF.sub.4.sup.- or .sup.-.
A precipitated, solid bisdiazonium salt of the formula ##STR8## in which R denotes propyl or butyl, and X.sup.- denotes BF.sub.4.sup.- or .sup.-.
Dependencies are inferred from the claim text.