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AssigneeInstitut Francais du Petrole
InventorsJacques Alagy, Christian Busson, Michel Fouquet
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A process for thermally converting methane e.g., at 1,000.degree.-1,300.degree. C. into hydrocarbons with higher molecular weights, especially ethylene comprises circulating a gas containing methane in ceramic channels (11) grouped in rows which cover at least a part of the reactor (1) length, parallel to its axis. At the reaction temperature, the temperature variation is kept at less than 20.degree. C. The rows of channels form multiple plates (4) which are not adjacent to one another and which define tight spaces (17) in which are housed the electric heating (5, 22) means that heat the channel plates in a first zone (9) through successive, independent cross sections substantially perpendicular to the axis of the reactor and substantially parallel to the plane of the plates. Means for heating, servocontrol and modulation (7, 8) regulate the heating system. At the exit of the heating zone (9), the effluent is cooled in a second zone (10) equipped with cooling means and finally collected.
A process for thermally converting methane into hydrocarbons with higher molecular weights in a ceramic reaction zone having an axis and provided with parallel rows of channels extending over at least a part of the total reaction zone said channels being lengthwise parallel to said axis and to each other, said rows of channels being spaced from one another, the reaction zone also comprising a heating zone in indirect heat exchange contact with said rows of channels and a cooling zone which is an extension of said heating zone and is in indirect heat exchange contact with said rows of channels, comprising circulating a gas containing methane in the channels of said rows, heating the heating zone with an electric power supply through successive, independent transverse sections which are substantially perpendicular to the axis of said reaction zone and in indirect heat exchange contact with the channels of the reaction zone, so that a first part of the heating zone is maintained at a maximum temperature above 650.degree. C. to at most 1,500.degree. C., at a temperature gradient ranging from 5.degree. C./cm to 60.degree. C./cm on a length from 5 to 50% of the total heating zone length, and wherein a second part of the heating zone, following said first part is heated at substantially said maximum temperature so that the temperature variation all along said second part is less than about 20.degree. C., and said circulated gas is heated to the maximum temperature introducing a cooling fluid into said cooling zone and collecting said hydrocarbons with higher molecular weights at the end of the reaction zone.
In a process for thermally converting methane to hydrocarbons having higher molecular weights, the step of passing a gas containing methane through an elongated heating zone, wherein in a first part of the heating zone, the gas is heated up to a maximum temperature above 650.degree. C. to at most 1,500.degree. C., at a thermal gradient ranging from 5.degree. C./cm to 60.degree. C./cm on a length from 5 to 50% of the total heating zone length, and wherein in a second part of the heating zone, subsequent to said first part, the gas is heated at substantially the maximum temperature with a temperature variation all along said second part lower than about 20.degree. C.
Dependencies are inferred from the claim text.