Non-porous metal-oxide coated carbonaceous fibers and applications in ceramic matrices
OwnerThomas M. Sullivaninventor
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Abstract
Non-porous metal oxide-coated carbonaceous fibers capable of withstanding chemical degradation at temperatures above 1600.degree. C. and that are particularly useful in the construction of ceramic or metal composites without carbon-carbide hypereutectic formation or micro-cracking in metal and ceramic matrix composites, respectively, but with good interfacial bonding, thereby allowing the same to be favorably employed in space reentry vehicles, heat shields, high-performance aircraft, internal combustion engines, and the like.
Claims7
A ceramic matrix composite capable of withstanding chemical degradation at temperatures greater than 1600.degree. C., comprising:
- metal oxide-coated carbonaceous fibers, and
- ceramic matrix material in contact with said metal oxide-coated carbonaceous fibers wherein said metal oxide-coated carbonaceous fibers occupy from greater than 0% up to about 55% by volume of said ceramic matrix composite.
A ceramic matrix composite capable of withstanding chemical degradation at temperatures greater than 1,600.degree. C., comprising:
- (a) metal oxide-coated carbonaceous fibers comprising a carbonaceous fiber in contact with about a 250-Angstrom thick contiguous non-porous metal oxide layer composed of materials selected from the group consisting of MgO, BeO, Group IIIA oxides excluding oxides of actinides with Atomic Numbers higher than 92, Group IIIB oxides excluding thalium oxide and borium oxide, and Group IVA oxides excluding titanium oxide and alloys thereof;
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- (b) ceramic matrix material in contact with said metal oxide-coated carbonaceous fibers, said carbonaceous fibers being selected from the group consisting of carbide, graphite or carbon and wherein said metal oxide-coated carbonaceous fibers occupy from greater than 0% up to about 55% by volume of said ceramic matrix composite;
- (c) said ceramic matrix being composed of materials selected from the group consisting of metal oxides, oxynitrides, nitrides, borides and carbonitrides.
A ceramic matrix composite capable of withstanding chemical degradation at temperatures greater than 1,600.degree. C., comprising:
- (a) metal oxide-coated carbonaceous fibers comprising a carbonaceous fiber in contact with about a 250-Angstrom thick contiguous non-porous metal oxide layer composed of materials selected from the group consisting of MgO, BeO, Group IIIA oxides excluding oxides of actinides with Atomic Numbers higher than 92, Group IIIB oxides excluding thalium oxide and borium oxide, and Group IVA oxides excluding titanium oxide and alloys thereof;
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- (b) ceramic matrix material in contact with said metal oxide-coated carbonaceous fibers, said carbonaceous fibers being selected from the group consisting of carbide, graphite or carbon and wherein said metal oxide-coated carbonaceous fibers occupy from greater than 0% up to about 55% by volume of said ceramic matrix composite;
- (c) said ceramic matrix being composed of materials selected from the group consisting of BeO, Al.sub.2 O.sub.3, LiAlSi.sub.2 O.sub.6, SiAlON, Al.sub.6 Si.sub.2 O.sub.13, ZrSiO.sub.4, SiC, Si.sub.3 N.sub.4, transformation toughened ZrO.sub.2, transformation toughened Al.sub.2 O.sub.3, Si.sub.3 N-SiO.sub.2 -Y.sub.2 O.sub.3, ThO.sub.2, TiB.sub.2, ZrB.sub.2, HfB.sub.2, TiC, Cr.sub.3 C.sub.2, TiN, Cordierite, Fe.sub.2 O.sub.3, AlN, and Fe.sub.3 O.sub.4.
A ceramic matrix composite capable of withstanding chemical degradation at temperatures greater than 1,600.degree. C., consisting essentially of:
- metal oxide-coated carbonaceous fibers, and
- ceramic matrix material in contact with said metal oxide-coated carbonaceous fibers wherein said metal oxide-coated carbonaceous fibers occupy from greater than 0% up to about 55% by volume of said ceramic matrix composite.
Dependencies are inferred from the claim text.