Hydrogenation process
AssigneeDavy McKee (London) Limited
InventorsGeorge E. Harrison, John R. Hensman
Life of this patent
Estimating the term…
Abstract
Hydrogen is supplied first to a last hydrogenation zone, and gases recovered from the last hydrogenation zone are passed to the first hydrogenation zone of a continuous multi-zone liquid phase process for hydrogenating an organic compound to a corresponding hydrogenation product. The organic compound, with a suitable diluent or recycle hydrogenation product, flows successively through the zones beginning with the first and ending with the last hydrogenation zone to undergo hydrogenation with the hydrogenation product being recovered from the last hydrogenation zone.
Claims12
A continuous process for hydrogenating an organic compound which can be hydrogenated in a liquid phase to a corresponding hydrogenation product, the process comprising:
- (a) providing a hydrogenation plant comprising first and second hydrogenation zones connected in series each containing a charge of a solid heterogeneous hydrogenation catalyst;
- (b) continuously supplying to an upper part of the first hydrogenation zone (i) a hydrogen-containing gas and (ii) a liquid phase containing the organic compound dissolved in a compatible diluent therefor;
- (c) maintaining the first hydrogenation zone under temperature and pressure conditions conductive to hdyrogenation;
- (d) allowing liquid phase to pass downwardly through the first hydrogenation zone;
- (e) continuously recovering an intermediate reaction product from a lower part of said first hydrogenation zone;
- (f) recovering a gaseous effluent from a lower part of the first hydrogenation zone;
- (g) supplying intermediate reaction product from step (e) in liquid form to an upper part of said second hydrogenation zone;
- (h) maintaining the second hydrogenation zone under temperature and pressure conditions conductive to hydrogenation;
- (i) allowing intermediate liquid reaction product to pass downwardly through said second hydrogenation zone;
- (j) supplying a hydrogen-containing feed gas to an upper part of the second hydrogenation zone;
- (k) recovering a gaseous effluent stream from a lower part of the second hydrogenation zone;
- (l) supplying material of the gaseous effluent stream of step (k) to form the hydrogen-containing gas of step (b);
- (m) recovering a liquid hydrogenation product containing stream from a lower part of the second hydrogenation zone;
- and
- (n) purging material of the gaseous effluent stream of step (f) from the hydrogenation plant.
A continuous process for hydrogenating an organic compound selected from the group consisting of aldehydes, unsaturated hydrocarbons, unsaturated fatty acids, ketones and esters of unsaturated fatty acids to a corresponding hydrogenation product, the process comprising:
- passing the organic compound in a liquid phase successively through first and second hydrogenation zones containing a respective charge of a solid heterogeneous hydrogenation catalyst;
- passing a stream of hydrogen-containing gas through the second hydrogenation zone co-current with the flow of liquid phase organic compound;
- maintaining the second hydrogenation zone under temperature and pressure conditions producing hydrogenation of the organic compound;
- passing hydrogen-containing gas recovered from the second hydrogenation zone through the first hydrogenation zone co-current with the flow of liquid phase organic compound;
- maintaining the first hydrogenation zone under temperature and pressure conditions producing hydrogenation of the organic compound;
- purging gas from the first hydrogenation zone;
- and
- recovering the liquid hydrogenation product from the second hydrogenation zone.
Dependencies are inferred from the claim text.