Coupling process
AssigneeEthyl Corporation
InventorsJames S. Staton, Ronald A. Turnblad, Jr., Robert B. Agee
Life of this patent
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Abstract
An alkene is coupled with an aromatic hydrocarbon having an active hydrogen on a saturated alpha-carbon in the presence of an unsupported alkali metal as a catalyst under high shear agitation conditions. In preferred embodiments of the invention, the alkene is an alkene of 2-20 carbons, such as ethene or propene; the active hydrogen-containing aromatic hydrocarbon is an alkyl-benzene, such as toluene; the alkali metal is potassium or a potassium alloy; and the high shear agitation conditions are attained by operating a turbine-type impeller at a tip speed of at least about 5 m/sec.
Claims16
In a process for coupling an alkene with an aromatic hydrocarbon having an active hydrogen on a saturated alpha-carbon in the presence of an unsupported alkali metal as a catalyst, the improvement which comprises subjecting the reaction mixture to high shear agitation with an agitator having a tip speed of at least about 5 m/sec.
Dependencies are inferred from the claim text.