Difluoroalkane and difluoroalkenylalkane pesticides
AssigneeFMC Corporation
InventorsClinton J. Peake, Thomas G. Cullen, Anthony J. Martinez
Life of this patent
Estimating the term…
Abstract
The present invention discloses compounds of the formula ##STR1## in which R is a 1,1-difluoroalkyl group or a 1,1-difluoroethenyl group having an even numbered carbon chain length of from 4 to 22 carbon atoms, pesticidal compositions thereof; and their use to control plant pests such as insects, acarids, and nematodes.
Claims12
A difluoroalkane or difluoroalkenylalkane derivative of the structural formula I ##STR26## in which R is a 1,1-difluoroalkyl group of 1 to 3 carbon atoms or a 1,1-difluoroalkenyl group of 2 to 4 carbon atoms, optionally carrying a halogen substituent selected from bromine and chlorine, m is an integer which produces a carbon chain length for the group R(CH.sub.2).sub.m which is an even number in the range of 2 to 20, Y is --NR.sup.1 --, or --O--, R.sup.1 is hydrogen or lower alkyl, and R.sup.2 is:
- (a) hydrogen, an alkali metal, or ammonium,
- (b) alkyl of 1 to 12 carbon atoms,
- (c) lower alkyl substituted with halogen, trifluoromethyl, ethenyl, difluoroethenyl ethynyl, lower alkoxy, C.sub.3 -C.sub.6 cycloalkyl which may be fluoro-substituted, lower alkylcarbonyl, lower alkoxycarbonyl, hydroxycarbonyl, cyano, phenylmethylfuryl, phenoxy, halophenoxy, phenyl, halophenyl, C.sub.1 -C.sub.2 alkoxyphenyl, thienyl, halothienyl, or a cyclopropyl group and a phenyl group which may be substituted with a substituent selected from halogen, methyl, trifluoromethyl and trifluoromethoxy, or a methyl group substituted with phenylmethyl and hydroxycarbonyl,
- (d) phenyl which may be substituted with one to three substituents independently selected from lower alkyl, halogen, lower alkoxy, formyl, nitro, hydroxycarbonylethenyl, lower alkoxycarbonylethenyl, and lower alkylamino(lower)alkoxycarbonyl,
- (e) pyridyl which may be substituted with halogen,
- (f) a group of the formula --SO.sub.2 R.sup.3 in which R.sup.3 is phenyl or phenylmethyl in which the ring may be substituted with a substituent selected from the group consisting of lower alkyl, halogen, and lower alkoxy, thienyl, pyridyl, or lower alkyl,
- (g) a group of the formula --N.dbd.CR.sup.4 R.sup.5 in which R.sup.4 is amino or dimethylamino and R.sup.5 is phenyl or phenylmethyl optionally ring substituted with lower alkoxy or trifluoromethoxy, or thienyl,
- (h) a group of the formula --C(SR.sup.6).dbd.NR.sup.7 in which R.sup.6 is lower alkyl or F.sub.2 C.dbd.CFC.sub.2 H.sub.4 and R.sup.7 is lower alkylcarbonyl or phenyl which may be substituted with a halogen atom,
- (i) a group of the formula --NR.sup.8 R.sup.9 in which R.sup.8 is hydrogen or lower alkyl, R.sup.9 is hydrogen, lower alkyl, alkylaminocarbonyl, phenylcarbonyl, F.sub.2 C.dbd.CHC.sub.3 H.sub.6 C(O)-- or acetyl,
- (j) a substituent selected from fluoroethoxy, F.sub.2 ClCCH.dbd.CHC.sub.9 H.sub.18 --, F.sub.2 C.dbd.CHC.sub.10 H.sub.20 --, 2,2-dimethyl-2,3-dihydrobenzofuranyl, 2,2-dimethyl-2,3-dihydrobenzofuranyloxycarbonyl, dimethoxyindanyl, and ##STR27## or Y and R.sup.2 taken together are hydrogen or form a nitrogen containing group selected from (lower)alkenylamino, piperidyl, pyrrolidinyl, or thiomorpholinyl.
Dependencies are inferred from the claim text.