Morphology-controlled olefin polymerization catalyst
AssigneeAmoco Corporation
InventorsSteven A. Cohen, Gregory G. Arzoumanidis, Nicholas M. Karayannis, Habet M. Khelghatian, Sam S. Lee
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AssigneeAmoco Corporation
InventorsSteven A. Cohen, Gregory G. Arzoumanidis, Nicholas M. Karayannis, Habet M. Khelghatian, Sam S. Lee
Estimating the term…
In a solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprising the product formed by (A) forming a solution of a magnesium-containing species from a magnesium alkyl (or hydrocarbyl) carbonate or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing toluene-based solvent by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic either; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor, the morphology of such component is modified by incorporating a morphology-affecting amount of C.sub.8 -C.sub.10 aromatics within the toluene-based solvent in Step B, Step A, in Step C prior to addition of ether, or combinations thereof.
A solid, hydrocarbon-insoluble alpha-olefin polymerization catalyst component comprises a product formed by:
A solid, hydrocarbon-insoluble alpha-olefin polymerization catalyst component comprises a product formed by:
Dependencies are inferred from the claim text.