Novel lubricant epoxides
AssigneeMobil Oil Corporation
InventorsNoyes L. Avery, Andrew G. Horodysky, Derek A. Law, Leslie R. Rudnick
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AssigneeMobil Oil Corporation
InventorsNoyes L. Avery, Andrew G. Horodysky, Derek A. Law, Leslie R. Rudnick
Estimating the term…
Epoxy functionalized polyalpha-olefin lubricants compositions are prepared with superior properties by epoxidizing the olefinic bond of oligomers prepare by oligomerizing C.sub.6 -C.sub.20 alpha-olefins with reduced valence state chromium catalyst on silica support. The invention encompasses a product of reaction made by epoxidizing C.sub.30 + polyalpha-olefin oligomeric hydrocarbon lubricant having a branch ratio of less than 0.19 and pour point below -15.degree. C. in the presence of an epoxidizing amount of an epoxidizing agent wherein said product comprises a mixture of 2-dialkyl oxirane and 1,2-dialkyl oxirane having between an average of C.sub.30 and C.sub.1000 carbon atoms, said mixture having a branch ratio of less than 0.19 and pour point below -15.degree. C. The invention further encompasses blends and additive compositions of the novel epoxidizing polyalpha-olefins.
A product of reaction made by epoxidizing C.sub.30 + polyalpha-olefin oligomeric hydrocarbon lubricant having a branch ratio of less than 0.19 and pour point below -15.degree. C. in the presence of an epoxidizing amount of an epoxidizing agent wherein the product has a weight average molecular weight between 300 and 150,000 number average molecular weight between 300 and 30,000 and molecular weight distribution between 1 and 5.
A lubricant composition comprising a mixture of 2-dialkyl oxirane and 1,2-dialkyl oxirane having between an average of 30 and 1000 carbon atoms, a branch ratio of less than 0.19, pour point of less than -15.degree. C. and VI above about 130.
A lubricant composition containing the recurring polymeric structures ##STR4## where m is 3 to 12 and where the combination of n recurring units is 3 to 500.
A method for decreasing wear and reducing friction in an internal combustion engine by lubricating said engine with a friction reducing amount of a product of reaction made by epoxidizing C.sub.30 + polyalpha-olefin oligomeric hydrocarbon lubricant having a branch ratio of less than 0.19 and pour point below -15.degree. C. in the presence of an epoxidizing amount of an epoxidizing agent.
A method for scavenging water and decreasing corrosion in an internal combustion engine by lubricating said engine with a lubricant containing a water reactive amount of a product of reaction made by epoxidizing C.sub.30 + polyalpha-olefin oligomeric hydrocarbon lubricant having a branch ratio of less than 0.19 and pour point below -15.degree. C. in the presence of an epoxidizing amount of an epoxidizing agent.
A lubricant mixture having enhanced viscosity index comprising,
Dependencies are inferred from the claim text.