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AssigneeSumitomo Chemical Company, Limited
InventorsTakashi Omura, Katsumasa Otake, Kaneo Yokoyama, Yasuo Tezuka
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A reactive metal formazan blue dye represented by a free acid of the formula, ##STR1## wherein A.sub.1 and A.sub.2 are independently a substituted or unsubstituted phenylene or naphthylene group, B is a straight or branched alkyl or alkenyl group, a phenyl group, a naphthyl group or a heterocyclic group, the alkyl, alkenyl, phenyl, napthyl and heterocyclic group being substituted or unsubstituted, Me is an ion of metal identified by an atomic number of 27 to 29, X is --O-- or ##STR2## Y is a halogen atom, Z is a group capable of imparting water solubility, each of l, m and n is 0 or an integer of 1 to 3, provided that the sum of l, m and n is from 1 to 4, D is a substituted or unsubstituted phenylene or naphthylene group, R is a substituted or unsubstituted lower alkyl group, and Q is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 L in which L is a group capable of being splitted by the action of alkali, which is useful for dyeing hydroxy- or amido-containing fiber materials with good build-up and level-dyeing properties to obtain a dyed product of deep blue color having excellent fastness, particularly against light, perspiration-light and chlorine.
A compound represented by a free acid of the formula, ##STR90## wherein A.sub.1 and A.sub.2 are independently phenylene unsubstituted or substituted with one substituent selected from the group consisting of chlorine, bromine, nitro, methyl ethyl, methoxy, ethoxy sulfonyl, N,N-dimethylsulfamoyl, B is phenyl unsubstituted or substituted with one or two members selected from the group consisting of chlorine, methyl ethyl, methoxy, ethoxy, carbomethoxy, carboethoxy, and nitro, Me is a copper ion, X is --O--, or ##STR91## Y is fluorine or chlorine, Z is sulfonic acid, carboxylic acid or phorphoric acid, each of l, m and and n is 0 or an integer of 1 to 3, provided that the sum of I, m and n is from 2 to 3, D is phenylene unsubstituted or substituted with one or two members selected from the group consisting of methyl, ethyl, methoxy, ethoxy, chlorine and bromine, or nephthylene unsubstituted or substituted with sulfonic acid group, R is lower alkyl unsubstituted or substituted with hydroxy, carboxy, sulfo, carbamoyl, cyano or methoxycarbonyl, and Q is --SO.sub.23 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H.
A compound represented by a free acid of the formula, ##STR92## wherein R is lower alkyl unsubstituted or substituted with hydroxy, carboxy, sulfo, carbamoyl, cyano or methoxycarbonyl, D.sub.1 methoxy, ethoxy, chlorine or bromine, or naphthylene unsubstituted or substituted with sulfonic acid group, Q is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H, Y.sub.1 is fluorine or chlorine, and each of p, q and r is 0 or 1, provided that the sum of p, q and r is from 2 to 3.
A compound represented by the free acid of the formula, ##STR93## wherein R is lower alkyl unsubstituted or substituted with hydroxy, carboxy, sulfo, carbamoyl, cyano or methoxycarbonyl, D.sub.1 is phenylene unsubstituted or substituted with methyl, ethyl, methoxy, ethoxy group, chlorine or bromine, or naphthylene unsubstituted or substituted with sulfonic acid group, Q is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H, Y.sub.1 is a fluorine or chlorine atom, and each of p and q is 0 or 1.
A compound represented by a free acid of the formula, ##STR94## wherein R.sub.1 is a methyl, ethyl, carbamoylethyl, hydroxyethyl or n- or iso-propyl group, and Q is --SO.sub.2 CH.dbd.CH.sub.2 SO.sub.2 CH.sub.2 CH.sub.2 OSOhd 3H.
A compound represented by a free acid of the formula, ##STR95##
A compound represented by a free acid of the formula, ##STR96##
A compound represented by a free acid of the formula, ##STR97##
A compound represented by a free acid of the formula, ##STR98##
Dependencies are inferred from the claim text.