Carbamate physical property-improving reagent
AssigneeNippon Paint Co., Ltd.
InventorsSatoshi Urano, Ryuzo Mizuguchi, Noriyuki Tsuboniwa, Kei Aoki, Yuji Suzuki, Takeyasu Itoh
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Abstract
A physical property-improving reagent which comprises an alkenoylcarbamate compound of the formula: ##STR1## wherein R is a hydrogen atom or a lower alkyl group, X is an oxygen atom (--O--), a sulfur atom (--S--) or a substituted or unsubstituted imino group (--NR'--), R' being a hydrogen atom or a lower alkyl group, and Y is the residue of an active hydrogen atom-containing compound excluding --X-H therefrom dissolved in an organic solvent having a solubility parameter of not less than 8, which can impact excellent physical properties to a polymer produced with the same.
Claims20
An alkenoylcarbamate compound of the formula:
- ##STR48## wherein R is hydrogen or lower alkyl and R.sup.1 is stearyl, lower alkenyl, or phenyl.
An alkenoylcarbamate compound of the formula:
- ##STR49## wherein R is lower alkyl and R.sup.2 is glycidyl or glycidyloxy(lower)alkyl.
An alkenoylcarbamate compound of the formula:
- ##STR50## wherein R is hydrogen or lower alkyl and R.sup.3 is di(lower)-alkylamino(lower)alkyl, di(lower)alkylaminophenyl, lower alkylphenylamino(lower)alkyl, lower alkyl-phenyl(lower)-alkylamino(lower)alkyl, pyrrolidino, piperidino, morpholino, pyrrolidino(lower)alkyl, piperidino(lower)alkyl, morpholino(lower)alkyl, di(lower)alkylamino(lower)alkoxy(lower)alkyl or 2-(8-methyl-8-azabicyclo{3.2.1}oct-3-yloxycarbonyl)-2-phenylethyl.
An alkenoylcarbamate compound of the formula:
- ##STR51## wherein R is hydrogen or lower alkyl and R.sup.4 and R.sup.5 are each hydrogen, lower alkyl, lower alkenyl, phenyl(lower)alkyl, phenyl or lower alkanoyl, or R.sup.4 and R.sup.5 are taken together to form a lower alkylene chain.
An alkenoylcarbamate compound of the formula:
- ##STR52## wherein R is hydrogen or lower alkyl and R.sup.6 is lower alkyl, stearyl, cyclo(lower)alkyl, lower alkenyl, phenyl(lower)alkyl, phenyl or nephthyl.
An alkenoylcarbamate compound of the formula:
- ##STR53## wherein R is hydrogen or lower alkyl and R.sup.7 and R.sup.8 are each hydrogen, lower alkyl, stearyl, cyclo(lower)alkyl, lower alkenyl, phenyl(lower)alkyl, phenyl or thiazolyl, or R.sup.7 and R.sup.8 are taken together with the nitrogen atom to which they are attached to form a morpholino group.
An alkenoylcarbamate compound of the formula:
- ##STR54## wherein R is hydrogen or lower alkyl, R.sup.9 is hydrogen, alkyl of not more than 18 carbon atoms, lower alkenyl, phenyl or phenyl(lower)alkyl and R.sup.10 is hydrogen, or R.sup.9 and R.sup.10 are taken together to form a lower alkylene chain, provided that when R is hydrogen, R.sup.9 is not lower alkenyl.
An alkenoylcarbamate compound of the formula:
- ##STR55## wherein R, R.sup.11, R.sup.12, R.sup.13 and R.sup.14 are each hydrogen or lower alkyl.
An alkenoylcarbamate compound of the formula:
- ##STR56## wherein R is hydrogen or lower alkyl and Rb is a blocking group effected by excluding an active hydrogen atom from etherified alcohols, aromatic alcohols, active methylene compounds, lactams, N-hydroxyimides, oximes, imidazoles, triazoles or amines.
An alkenoylcarbamate compound of the formula:
- ##STR57## wherein R is hydrogen or lower alkyl and Rf is a fluorine atom-containing group effected by excluding an active hydrogen atom from 1,1,1,3,3,3-hexafluoroisopropanol, o-aminobenzotrifluoride, m-aminobenzotrifluoride, p-aminobenzotrifluoride, 2-amino-5-bromobenzotrifluoride, 3-amino-4-bromobenzotrifluoride, 5 amino-2-bromotrifluoride, 2-amino-5-chlorobenzotrifluoride, 3-amino-4-chlorobenzotrifluoride, 5-amino-2- chlorobenzotrifluoride, 2 amino-5-fluorobenzotrifluoride, 3-amino-4-fluorobenzotrifluoride, 5-amino-2-fluorobenzotrifluoride, 3-amino-5-methoxybenzotrifluoride, 2-amino-5-nitrobenzo-trifluoride, 4-amino 3-nitrobenzotrifluoride, 5-amino-2-nitrobenzotrifluoride, 4 amino-2,3,5,6-tetrafluorobenzamide, 4-amino-2,3,5,6-tetrafluorobenzoic acid, 4-amino-2,3,5,6-tetrafluorobenzonitrile, bis(trifluoromethylacetamide), chlorodifluoroacetamide, chlorodifluoroacetic acid, 3-chloro-4-fluoroaniline 2-chloro-6-fluorobenzoic acid, 3-chloro-4-fluorobenzoic acid, 2-chloro-6-fluorobenzyl alcohol, 2-chloro-4-fluorophenol, 2-chloro-6-fluorophenylacetic acid, 1-chloro-3-fluoro-2-propanol, 4 chloro-3-hydroxybenzotrifluoride, decafluorobenzhydrol, 3,4-diaminobenzotrifluoride, 3,5-diaminobenzotrifluoride, 4,4,-diamino-octafluorobiphenyl, 1,3-dichlorotetrafluoroisopropanol, difluoroacetic acid, 2,4-difluoroaniline, 2,5-difluoroaniline, 2,6-difluoroaniline, 2,4-difluorobenzamide, 2,5-difluorobenzamide, 2,6-difluorobenzamide, 3,4-difluorobenzamide, 2,4-difluorobenzoic acid, 2,5-difluorobenzoic acid, 2,6-difluorobenzoic acid, 3,4-difluorobenzoic acid or 1H,1H-oentadecafluorooctanol.
An alkenoylcarbamate compound of the formula:
- ##STR58## wherein R is hydrogen or lower alkyl and Rm is a triazine skeleton-containing group effected by excluding an active hydrogen atom from melamine, methylolated melamines, lower alkoxymethyloimelamines or guanamines.
An alkenoylcarbamate compound of the formula:
- ##STR59## wherein R is hydrogen or lower alkyl and Rnc is a non-contractive structure-containing group effected by excluding an active hydrogen atom from the compounds of the formulas:
- ##STR60## wherein R.sup.15 and R.sup.16 are each hydrogen or lower alkyl and n is an integer of 3 to 5.
An alkenoylcarbamate compound of the formula:
- ##STR61## wherein R is hydrogen or lower alkyl and Rp is a photosensitive group or structure effected by excluding an active hydrogen atom from an olefin, cinnamoyl, cinnamylidene, cinnamylideacetyl, furylacryloyl, coumarine, pyron, benzalacetophenone, styrilpyridine, anthracene, stilben, alpha-phenylmaleimide, azide, phenylazide, sulfonylazide, carbonylazide, diazo, alpha-quinonediazide benzophenone, benzoin, 1,3-dioxane, dithiocarbamate, xanthete, 1,2,3-thiadiazole, cyclopropene, azadioxabicyclo or spiropyran.
An alkenoylcarbamate compound of the formula:
- ##STR62## wherein R is methyl and R.sup.1 is stearyl, lower alkenyl or phenyl.
Dependencies are inferred from the claim text.