Organic photochromic pigment particulates
AssigneePPG Industries, Inc.
InventorsRonald L. Haynes, Charles H. Hoelscher, Jonathan G. Lasch
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AssigneePPG Industries, Inc.
InventorsRonald L. Haynes, Charles H. Hoelscher, Jonathan G. Lasch
Estimating the term…
Described is photochromic particulate material comprising a photochromic substance within a matrix of a polymerizate of a polyfunctional acrylate monomer. The photochromic particulate material may be produced by adding an organic photochromic substance to a polymerizable composition including a polyfunctional acrylate monomer and polymerizing the resultant admixture, e.g., by emulsion polymerization. In the case of emulsion or suspension polymerization, finely divided particulate organic photochromic materials are separated from the polymerization medium in the form of spheroidal thermoset photochromic particles of fairly uniform size. If desired, the particles recovered from the polymerization medium may be further ground in conventional attrition mills to further reduce the size of the particulate product. In the case of bulk polymerization, the polymerizate may be formed as a continuously cast sheet, which is then pulverized to a particulate material of pigmentary size.
Photochromic particulate cross-linked thermostet resin having an average particle diameter between about 0.25 and 20 micrometers and having a photochromic amount of an organic photochromic substance uniformly dispersed throughout the particulate resin, said thermoset resin being a polymerizate of a polyfunctional acrylate monomer composition which is polymerized with a peroxygen or azo-type initiator in the presence of said photochromic substance, said polyfunctional acrylate monomer composition including at least one acrylate monomer represented by the following formula, ##STR17## wherein R is hydrogen or methyl, n is the number 2, 3 or 4 and R' is the multivalent radical remaining after removal of the hydroxy groups from a polyol having from 2 to 4 hydroxy groups.
A method for producing a photochromic particulate thermoset resin, which comprises dispersing a substantially uniform mixture of polyfunctional acrylate monomer composition and a photochromic amount of organic photochromic substance that is compatible with said monmer composition in an aqueous polymerization medium, polymerizing the monomer, with a peroxygen or azo-type initiator and separating finely-divided cross-linked thermoset photochromic particles from the polymerization medium, said polyfunctional acrylate monomer being represented by the following formula, ##STR18## wherein R is hydrogen or methyl n is the number 2, 3 or 4 and R' is the multivalent radical remaining after removal of the hydroxy groups from a polyol having from 2 to 4 hydroxy groups.
Dependencies are inferred from the claim text.