In the fabrication of a back surface point contact solar cell including a silicon substrate and employing silicon oxide and silicon nitride passivation layers, a method of reducing the recombination velocity of electron-holes pairs at the interface of the silicon substrate and the silicon oxide layer, comprising the steps of
- placing the silicon substrate with silicon oxide and silicon nitride layers thereon in a hydrogen atmosphere, and
- heating said silicon substrate in said atmosphere at a temperature of at least 900.degree. C. to diffuse hydrogen atoms through said silicon nitride layer and through said silicon oxide layer to the interface of said silicon oxide layer and said substrate.