Permanent magnet manufacture from very low coercivity crystalline rare earth-transition metal-boron alloy
AssigneeGeneral Motors Corporation
InventorsPeter Vernia, Robert W. Lee
Life of this patent
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Abstract
A method is disclosed of hot working a magnetically soft cast crystalline material containing grains of RE.sub.2 TM.sub.14 B and an RE metal, rich intergranular second phase into anisotropic permanent magnet bodies.
Claims9
A method of processing alloys based on rare earth elements, iron and boron to make permanent magnets, the method comprising hot working a magnetically soft crystalline material consisting essential of grains of RE.sub.2 TM.sub.14 B where RE is one or more rare earth elements at least 60 percent of which is neodymium and/or praseodymium, TM is a transition metal at least 60 percent of which is iron, and B is the element boron, which grains have an average length greater than about 5 microns in the direction of the crystallographic c-axis and are separated by an intergranular layer of a material richer in rare earth elements than the RE.sub.2 TM.sub.14 B grains, the material initially having no more than 500 Oe coercivity, said working being carried out at an elevated temperature above the melting temperature of the intergranular phase and at a pressure such that material acquires coercivity in excess of 1000 Oe.
A method of processing alloys based on rare earth elements, iron and boron to make permanent magnets, the method comprising working a crystalline magnetically soft material the grains of the principal phase of which are at least about 5 microns along their smallest dimension and which consist essentially of platelets of RE.sub.2 TM.sub.14 B where RE is one or more rare earth elements at least 60 percent of which is neodymium and/or praseodymium, TM is a transition metal at least 60 percent of which is iron, and B is the element boron, which are separated by an intergranular layer of a material richer in rare earth elements than the RE.sub.2 TM.sub.14 B grains, the material initially having no more than 500 Oe coercivity, said working being carried out at an elevated temperature above the melting point of the intergranular phase at a pressure such that material acquires coercivity in excess of 1000 Oe.
A method of making an anisotropic permanent magnet comprising
- chill casting a molten metal mixture containing rare earth elements, iron and boron in suitable proportions to form a solidified, crystalline magnetically soft alloy having a predominant phase consisting essentially of grains of RE.sub.2 TM.sub.14 B which have an average diameter of at least about 5 microns and where RE is one or more rare earth elements at least 60 percent of which is neodymium and/or praseodymium, TM is a transition metal at least 60 percent of which is iron, and B is the element boron, said grains each having a crystallographic c-axis and which grains are aggregated in regions where such axes are substantially parallel to one another, and a minor second phase between the said grains which is lower melting than the RE.sub.2 TM.sub.14 B phase,
- heating said alloy to an elevated temperature above the melting point of the second phase,
- mechanically working said alloy and deforming it such that the resulting body upon cooling is magnetically anisotropic and has a permanent magnet characteristics.
A method of making an anisotropic permanent magnet comprising
- chill casting a molten metal mixture containing rare earth elements, iron and boron in suitable proportions to form a solidified, crystalline magnetically soft alloy having a predominant phase consisting essentially of grains of RE.sub.2 TM.sub.14 B which have an average diameter of at least about 5 microns and where RE is one or more rare earth elements at least 60 percent of which is neodymium and/or praseodymium, TM is a transition metal at least 60 percent of which is iron, and B is the element boron, said grains each having a preferred axis of magnetic orientation along the crystallographic c-axis and which grains are aggregated in regions where such c-axes are substantially parallel to one another, and a minor second phase between the said grains which is relatively richer in rare earth elements than the RE.sub.2 TM.sub.14 B phase,
- heating said alloy to an elevated temperature above the melting point of the second phase,
- mechanically working said heated alloy and deforming it such that the alloy achieves magnetically hard properties and more grains are aligned with their c-axes parallel to increase magnetic alignment.
A method of making an anisotropic permanent magnet comprising
- chill casting a molten metal mixture containing rare earth elements, iron and boron in suitable proportions to form a fully crystalline, magnetically soft alloy having a predominant phase consisting essentially of packets of grains of RE.sub.2 TM.sub.14 B where RE is one or more rare earth elements at least 60 percent of which is neodymium and/or praseodymium, TM is a transition metal at least 60 percent of which is iron, and B is the element boron, said grains each having a preferred axis of magnetic orientation along their crystallographic c-axes, an average length greater than 5 microns measured along the c-axis, and which grains are aggregated in packets where their crystallographic c-axes are substantially parallel to one another, and a minor second phase between the said grains which is relatively richer in rare earth elements than the RE.sub.2 TM.sub.14 B phase,
- attriting said alloy to a coarse particles greater than about 50 microns in size which predominantly comprise single packets of grains,
- enclosing said particles in a malleable container,
- heating said container and alloy to an elevated temperature to melt the second phase,
- rolling said heated container to deform it such that the particles are compacted to near 100 percent density and anisotropic permanent magnet characteristics are induced in the alloy.
A method of making an anisotropic permanent magnet comprising directionally solidifying a molten metal mixture containing rare earth elements, iron and boron in suitable proportions to form a magnetically soft, crystalline alloy having a predominant phase, grains of said phase having an average diameter of at least about 5 microns and consisting essentially of platelets of RE.sub.2 TM.sub.14 B where RE is one or more rare earth elements at least 60 percent of which is neodymium and/or praseodymium, TM is a transition metal at least 60 percent of which is iron, and B is the element boron, said grains each having a crystallographic c-axis lying perpendicular to the large, flat faces of the platelets and a minor phase between the said grains which is relatively richer in rare earth elements than the RE.sub.2 TM.sub.14 B phase,
- heating said alloy to an elevated temperature to melt the second phase, and
- mechanically working said heated alloy such that it flows so as to align the crystallographic c-axes of the grains therein and such that the resulting body upon cooling is magnetically anisotropic and has permanent magnet characteristics.
A method of making an anisotropic permanent magnet comprising
- chill casting a molten metal mixture containing rare earth metals, iron and boron in suitable proportions to form a solidified, magnetically soft, crystalline alloy having a predominant phase consisting essentially of grains of RE.sub.2 TM.sub.14 B having an average diameter of at least about 5 microns where RE is one or more rare earth elements at least 60 percent of which is neodymium and/or praseodymium, TM is a transition metal at least 60 percent of which is iron, and B is the element boron, the grains having crystallographic c-axes and being aggregated in regions where their crystallographic c-axes are substantially parallel to one another, and a minor phase between the said grains which is lower melting than the RE.sub.2 TM.sub.14 B phase,
- attriting said alloy to coarse particles which predominantly comprise single packets of said grains and are greater than about 50 microns in size,
- enclosing said particles in a malleable container,
- heating said container and alloy to an elevated temperature to melt the second phase, and deforming said heated container such that the particles are compacted to near 100 percent density and anisotropic permanent magnet characteristics are induced in the alloy.
A method of making an anisotropic permanent magnet comprising
- directionally solidifying a molten metal mixture containing rare earth elements, iron and boron in suitable proportions to form a solidified, magnetically soft, fully crystalline alloy having a predominant phase consisting essentially of grains of RE.sub.2 TM.sub.14 B where RE is one or more rare earth elements at least 60 percent of which is neodymium and/or praseodymium, TM is a transition metal at least 60 percent of which is iron, and B is the element boron to form large grains which measure at least about 5 microns along their smallest average dimension and a minor phase between the said large grains which is lower melting than the RE.sub.2 TM.sub.14 B phase,
- heating said alloy to an elevated temperature to melt the second phase, and
- mechanically working said alloy such that it is deformed, whereby the resulting body upon cooling is magnetically anisotropic and has permanent magnetic characteristics.
A method of making an anisotropic permanent magnet comprising
- directionally solidifying a molten metal mixture containing rare earth elements, iron and boron in suitable proportions to form a solidified, low coercivity alloy having an average grain size of at least 5 microns and a predominant phase consisting essentially of platelets of RE.sub.2 TM.sub.14 B where RE is one or more rare earth elements at least 60 percent of which is neodymium and/or praseodymium, TM is a transition metal at least 60 percent of which is iron, and B is the element boron, said grains each having a crystallographic c-axis lying perpendicular to their faces, and a minor phase between the said grains which is lower melting than the RE.sub.2 TM.sub.14 B phase,
- heating said alloy to an elevated temperature to melt the second phase,
- mechanically working said heated alloy such that it flows to align the crystallographic c-axes of the grains therein whereby the resulting body upon cooling has permanent magnetic properties and has a preferred direction of magnetic orientation transverse to said direction of flow.
Dependencies are inferred from the claim text.