Adhesive containing isocyanate-terminated polyurethane prepolymer and epoxy resin
AssigneeHenkel Kommanditgesellschaft auf Aktien
InventorsHans-Guenter Seltmann, Hans-Josef Hoffmann, Hartmut Lippert
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Abstract
A moisture-hardening flocking adhesive composition for application to elastomers. The adhesive contains an isocyanate terminated polyurethane prepolymer, an aromatic dinitroso compound and an essentially hydroxyl-free epoxy resin having an epoxide value of from about 0.45 to about 0.75. The composition is essentially free of highly volatile organic solvents. The composition is characterized as having improved storage stability and provides excellent adhesion between elastomeric substrates and flocking fibers, even after exposure to water.
Claims17
An adhesive composition comprising:
- (a) at least one isocyanate terminated polyurethane prepolymer, said prepolymer consisting essentially of the reaction product of a diisocyanate component selected from the group consisting of diphenylmethane diisocyanate, hydrogenated diphenylmethane diisocyanate, tolyene diisocyanate, hexamethylene diisocyanate, and mixtures thereof with a mixture of difunctional polyols, one of said polyols having a number average molecular weight of from about 400 up to 1000, and another of said polyols having a number average molecular weight of from more than 1000 up to about 4000;
- (b) at least one aromatic dinitroso compound present in an amount sufficient to promote adhesion of the composition to an elastomeric substrate;
- (c) at least one epoxy resin having an epoxide value of from about 0.45 to about 0.75 and a hydroxide value of less than about 0.01;
- and
- (d) at least one alkyl benzene having the formula C.sub.6 H.sub.5 --C.sub.n H.sub.2n+1, where n is an integer having a value of 8 to 16,
- said adhesive composition being essentially free of catalysts which catalyze the reaction of NCO groups with epoxy groups to form oxazolidone groups.
A moisture hardening adhesive composition for use in the electrostatic flocking of flexible substrates, comprising:
- (a) from about 80 to about 96 parts by weight of a polyurethane prepolymer consisting essentially of the reaction product of a diisocyanate component selected from the group consisting of diphenylmethane diisocyanate, hydrogenated diphenylmethane diisocyanate, tolyene diisocyanate, hexamethylene diisocyanate, and mixtures thereof with a mixture of difunctional polyols, one of said polyols having a number average molecular weight of from about 400 up to 1000, and another of said polyols having a number average molecular weight of from more than 1000 up to about 4000;
- (b) from about 1 to about 5 parts by weight of at least one aromatic dinitroso compound;
- (c) from about 3 to about 10 parts by weight of at least one epoxy resin having an epoxide value of from about 0.45 to about 0.75 and a hydroxide value of less than about 0.01, selected from the group consisting of reaction products of epichlorhydrin with a novolak or a bisphenol;
- and
- (d) 0 to abut 20 parts by weight of at least one alkyl benzene having the formula C.sub.6 H.sub.5 --C.sub.n H.sub.2n+1, wherein n is an integer having a value of 8 to 16,
- parts by weight being based on a composition having 100 parts by weight, said moisture hardening adhesive composition being essentially free of catalysts which catalyze the reaction of NCO groups with epoxy groups to form oxazolidone groups.
Dependencies are inferred from the claim text.