Continuous monochrometer drift compensation of a spectral monochromator
AssigneeThe Perkin-Elmer Corporation
InventorsCharles E. Wuest, John B. Collins
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AssigneeThe Perkin-Elmer Corporation
InventorsCharles E. Wuest, John B. Collins
Estimating the term…
Iterative compensation of drift of peak positions of spectral lines is effected in a spectral monochromator including a grating, a detector of spectral fractions of a spectral band, a stepper motor for varying relative orientation of the grating and the detector, and a computer. Computer-defined spectral windows each encopasses a spectral band and has an initial spectral center. Each window is scanned to determine a peak spectral position. Calculation is made for determining a spectral position error of the peak position from the initial center for each corresponding window. A functional average of the offsets for the peaks is calculated as a linear function of window position, and a revised spectral center for each window is calculated as being equal to the initial center plus the functional average for the window position determined from the linear function. Each window is shifted correspondingly. The step of successively scanning through each window is repeated to determine a new peak position for each corresponding band, whereby each new peak position is maintained near the spectral center of each corresponding window.
A method of continuously compensating for drift of peak positions of spectral lines in a spectral monochromator including radiation means for generating elemental radiation for atomic elements, optical dispersion means receptive of the radiation for producing a series of spectral bands each having a peak spectral position associated with maximum radiation intensity, detector means selectively receptive of a spectral function of a spectral band for producing an intensity signal representative of the intensity of the spectral fraction being received, scanning means responsive of a scanning signal for varying relative orientation of the dispersion means and the detector means such that the series of spectral bands is scanned across the detector means in spectral positions corresponding to successive spectral fractions, and computer means receptive of the intensity signal for generating the scanning signal and calculating spectral position of each peak;
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