Fixed bed process for high viscosity index lubricant
AssigneeMobil Oil Corporation
InventorBruce P. Pelrine
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AssigneeMobil Oil Corporation
InventorBruce P. Pelrine
Estimating the term…
A process is disclosed to produce liquid oligomers from alpha-olefins feedstock, such as 1-decene, wherein said oligomers have branch ratios below 0.19 and have higher viscosity indices than oligomers with higher branch ratios. The olefins can be oligomerized over a supported and reduced metal oxide catalyst from Group VIB of the Periodic Table to give oligomers suitable for lubricant application. A preferred catalyst is lower valence state chromium on silica support. Surprisingly, it has been found that in the oligomerization of the alpha-olefins in a fixed bed reactor containing extruded catalyst the viscosity of the lubricant produced can be selectively controlled by carrying out the oligomerization at essentially constant oligomerization temperature while varying the olefin feedstock weight hourly space velocity (WHSV), based on catalyst, in correspondence with the preferred product viscosity.
In a process for the preparation of liquid hydrocarbons suitable as lubricant basestocks from alpha-olefin feedstock containing 6 to 20 carbon atoms, or mixtures of such olefins, comprising contacting said olefins under oligomerization conditions, at reaction temperature between 90.degree. to 250.degree. C. to vary product viscosity, and with a chromium catalyst on a porous support, which catalyst has been treated by oxidation at a temperature of 200.degree. C. to 900.degree. C. in the presence of an oxidizing gas and then by treatment with a reducing agent at a temperature and for a time sufficient to reduce said catalyst to a lower valence state to obtain an oligomeric liquid lubricant composition comprising C.sub.30 -C.sub.1300 hydrocarbons, said composition having a branch ratio of less than 0.19, weight average molecular weight between 420 and 18,000, molecular weight distribution between 1 and 5 and pour point below -15.degree. C., the improvement comprising;
A process for the production of liquid hydrocarbon basestock comprising;
Dependencies are inferred from the claim text.