Compositions comprising polyphenylene ethers, polyepoxides and aluminum or zinc diketone salt
AssigneeGeneral Electric Company
InventorsJohn E. Hallgren, Victoria J. Eddy, Jana M. Whalen
Life of this patent
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Abstract
Blends of high molecular weight polyphenylene ethers with various epoxy materials, particularly polyglycidyl ethers of bisphenolic compounds, are homogeneous at high temperatures and may be cured in the presence of a catalyst such as aluminum tris(acetylacetonate) or zinc bis(acetylacetonate), especially in the additional presence of an accelerator such as a basic nitrogen compound. The cured compositions have advantageous physical and electrical properties and are useful, for example, for the preparation of printed circuit boards.
Claims10
A curable composition consisting essentially of:
- (A) at least one polyphenylene ether having a number average molecular weight of at least about 12,000 to about 40,000, and
- (B) an epoxy material selected from the group consisting of (B-1) at least one polyglycidyl ether of a bisphenolic compound, said polyglycidyl ether having an average of at most one aliphatic hydroxy group per molecule, and combinations of a major amount of said polyglycidyl ether with a minor amount of at least one of (B-2) aryl monoglycidyl ethers and (B-3) non-bisphenolic polyepoxy compounds;
- and
- (C) an effective amount of a curing catalyst comprising an aluminum or zinc salt of a diketone of the formula ##STR7## wherein each of R.sup.3 and R.sup.4 is C.sub.1-20 alkyl or aryl and R.sup.5 is hydrogen or C.sub.1-20 alkyl or aryl;
- said composition comprising from 5 up to about 90% by weight of component A, based on components A and B, and having no other reactive materials.
A curable composition consisting essentially of:
- (A) at least one polyphenylene ether having a number average molecular weight of at least about 12,000 to about 40,000;
- (B) an epoxy material selected from the group consisting of (B-1) at least one polyglycidyl ether having an average of at most one aliphatic hydroxy group per molecule and combinations of a major amount of said polyglycidyl ether with a minor amount of at least one of (B-2) aryl monoglycidyl ethers and (B-3) non-bisphenolic polyepoxy compounds;
- (C) an effective amount of a curing catalyst comprising an aluminum or zinc salt of a diketone of the formula ##STR8## wherein each of R.sup.3 and R.sup.4 is C.sub.1-20 alkyl or aryl and R.sup.5 is hydrogen or C.sub.1-20 alkyl or aryl;
- and
- (D) at least one phenolic compound or basic nitrogen compound as a curing accelerator;
- said composition comprising from 5 up to about 90% by weight of component A based on components A and B, and having no other reactive materials.
Dependencies are inferred from the claim text.