# US 4,911,763 A · Process for producing a low alloy white cast iron > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,911,763 A - Document ID: US4911763A - Status: Granted - Kind: A - Application number: 07/219,456 - Filed: 1988-07-15 - Granted: 1990-03-27 - Earliest claimed: 1988-07-15 - Assignees: Norcast Corporation - Inventors: Jean C. Farge; Michel Lefebvre; Robert Fortin - Web page: https://patentgrep.com/patent/US4911763A ## CPC - C21D 1/60: Aqueous agents - C21D 5/04: of white cast-iron - C21D: MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING (surface treatment of metallic material involving at least one process provided for in class C23 and at least one process covered by this subclass C23F17/00; unidirectional solidification of eutectic materials or unidirectional demixing of eutectoid materials C30B) ## Abstract A process for producing a low alloy white cast iron is disclosed. The process comprises the steps of selecting one of a group of four alloying elements for a nickel, molybdenum/copper or modified low alloy iron; the four alloying groups consisting essentially, by weight percent of about: Group 1: 2.5 to 4.0% carbon; 0.3 to 0.8% silicon; 0.3 to 0.8% manganese; 0.75 to 2.0% nickel; 0 to 0.75% chromium. Group 2: 3.0 to 4.5% carbon; 0.3 to 0.8% silicon; 0.3 to 1.0% manganese; 0 to 0.8% molybdenum; and 0.3 to 1.0% copper. Group 3: 3.0 to 4.5% carbon; 0.3 to 0.8% silicon; 0.3 to 1.0% manganese; and 0.3 to 0.8% copper; the balance being iron except for incidental impurities commonly found in cast irons; melting the alloy; casting such alloy into moulds to produce the desired product; removing the product from the moulds while its surface temperature is above the transformation temperature of the alloy; and cooling it by quenching into a liquid medium containing water and an organic polymer at a sufficiently high rate to prevent the formation of pearlite but not so high as to generate cracks in the product. ## Claims ### Claim 1 A process for producing a low alloy white cast iron comprising: (a) melting an alloy consisting essentially of about 2.5 to 4.0% carbon, 0.3 to 0.8% silicon, 0.3 to 0.8% manganese, 0.75 to 1.5% nickel and 0 to 0.75% chromium; the balance of the alloy being iron except for incidental impurities commonly found in cast irons; (b) casting said alloy into moulds to produce the desired product; (c) removing the product from the moulds while its surface temperature is above the transformation temperature of the alloy; and (d) cooling the product by quenching into a liquid medium containing water and an organic polymer, said cooling being carried out at a sufficiently high rate to prevent the formation of pearlite but not so high as to generate cracks in the product, to enable subsequent transformation substantially totally to martensite and carbide, with a consequent hardness in excess of 600 Brinell. ### Claim 2 (depends on 1) A process as defined in claim 1, further comprising the step of heat treating the product at a temperature of 400.degree.-600.degree. F. for a time period of 4 to 8 hours. ### Claim 3 (depends on 2) A process as defined in claim 2, wherein the product is heat treated at a temperature of about 500.degree. F. for about 4 hours. ### Claim 4 (depends on 1) A process as defined in claim 1, wherein the products are grinding slugs in the size of 1 to 3 in, and wherein the cooling rate is in the range of 2.5.degree. to 25.degree. F./sec. ### Claim 5 (depends on 4) A process as defined in claim 4, wherein the alloying content and cooling rates are adjusted as a function of slug size, lower alloy content and high cooling rates being used with small slugs, and higher alloy content and low cooling rates with large slugs. ### Claim 6 (depends on 4) A process as defined in claim 4, wherein the volume of said organic polymer used in the liquid medium is in the range of 5 to 30%, said volume value increasing with increase in slug size. ### Claim 7 (depends on 4) A process as defined in claim 4, wherein the temperature of the liquid medium is kept in the range of 90.degree. to 130.degree. F. ### Claim 8 A process for producing a low alloy white cast iron comprising: (a) melting an alloy selected from one of three alloys, the first alloy consisting essentially of about 3.0 to 4.5% carbon; 0.3 to 0.8% silicon; 0.3 to 1.0% manganese; 0 to 0.8% molybdenum; and 0.3 to 1.0% copper; the second alloy consisting essentially of about 3.0 to 4.5% carbon; 0.3 to 0.8% silicon; 0.3 to 1.0% manganese; 0.25-0.45% nickel; 0 to 0.8% molybdenum; and 0.3 to 0.8% copper; the third alloy consisting essentially of about 3.0 to 4.5% carbon; 0.3 to 0.8% silicon; 0.3 to 1.0% manganese; 0.25 to 0.45% chromium; 0 to 0.8% molybdenum; and 0.3 to 0.8% copper, the balance of the three alloys being iron except for incidental impurities commonly found in cast irons; (b) casting said alloy into moulds to produce the desired product; (c) removing the product from the moulds while its surface temperature is above the transformation temperature of the alloy; and (d) cooling the product by quenching into a liquid medium containing water and an organic polymer, said cooling being carried out at a sufficiently high rate to prevent the formation of pearlite but not so high as to generate cracks in the product, to enable subsequent transformation substantially totally to martensite and carbide, with a consequent hardness in excess of 600 Brinell. ### Claim 9 (depends on 8) A process as defined in claim 8, further comprising the step of heat treating the product at a temperature of 400.degree.-600.degree. F. for a time period of 4 to 8 hours. ### Claim 10 (depends on 9) A process as defined in claim 9, wherein the product is heat treated at a temperature of about 500.degree. F. for about 4 hours. ### Claim 11 (depends on 8) A process as defined in claim 8, wherein the products are grinding slugs in the size of 1 to 3 in, and wherein the cooling rate is in the range of 2.5.degree. to 25.degree. F./sec. ### Claim 12 (depends on 11) A process as defined in claim 11, wherein the alloying content and cooling rates are adjusted as a function of slug size, lower alloy content and high cooling rates being used with small slugs, and higher alloy content and low cooling rates with large slugs. ### Claim 13 (depends on 11) A process as defined in claim 11, wherein the volume of said organic polymer used in the liquid medium is in the range of 5 to 30%, said volume value increasing with increase in slug size. ### Claim 14 (depends on 11) A process as defined in claim 11, wherein the temperature of the liquid medium is kept in the range of 90.degree. to 130.degree. F.