Siloxane polymer antifouling paint composition containing polysiloxanes
AssigneeKansai Paint Co., Ltd.
InventorsYoiti Yonehara, Kiyoshi Nanishi
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Abstract
An antifouling paint composition comprising as a film-forming component a vinyl-type copolymer obtained by copolymerization of (A) 1 to 50% by weight of a specific polymerizable unsaturated polysiloxane compound, (B) 0 to 30% by weight of a specific polymerizable unsaturated alkoxysilane compound, and (C) 20 to 99% by weight of a polymerizable unsaturated vinyl monomer other than the compounds (A) and (B) above.
Claims12
An antifouling paint composition comprising as a film-forming component a vinyl-type copolymer obtained by copolymerization of
- (A) 1 to 50% by weight of a polymerizable unsaturated polysiloxane compound represented by the formula ##STR26## wherein X.sub.1 represents a group of the formula ##STR27## where R.sub.6 represents a hydrogen atom or a methyl group;
- R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are identical or different and each represents an alkyl group having 1 to 4 carbon atoms, an aryl group or an aralkyl group;
- R.sub.5 represents a hydroxyalkyl group having 1 to 3 hydroxyl groups and 1 to 6 carbon atoms;
- a is 0 when X.sub.1 represents the group ##STR28## and an integer of 1 to 5 when X.sub.1 represents the group ##STR29## and b is a number of 3 to 1,000,
- (B) 0 to 30% by weight of a polymerizable unsaturated alkoxysilane compound represented by the formula ##STR30## wherein X.sub.2 represents a group of the formula ##STR31## where R.sub.8 represents a hydrogen atom or a methyl group;
- R.sub.7 represents an alkyl group having 1 to 4 carbon atoms;
- and
- d is 0 when X.sub.2 represents the group ##STR32## and an integer of 1 to 5 when X.sub.2 represents the group ##STR33## and (C) 20 to 99% by weight of a polymerizable unsaturated vinyl monomer other than the compounds (A) and (B) above,
- and further comprising 1 to 50 parts by weight, per 100 parts by weight of the vinyl-type copolymer, of a siloxane compound represented by the formula:
- ##STR34## wherein R.sub.10, R.sub.11, R.sub.12 and R.sub.13 are identical or different, and each represents an alkyl group having 1 to 4 carbon atoms, an aryl group or an aralkyl group;
- p is an integer of 1 to 5;
- and
- q is a number of 3 to 1,000 "and said composition being free of silanol-containing compounds".
The composition of claim 12 wherein R.sub.10, R.sub.11, R.sub.12 and R.sub.13 each represent a methyl group, p is an integer of 2 to 4, and q is a number of 30 to 500.
Dependencies are inferred from the claim text.