Diaminobenzoate catalytic chain extenders
AssigneeAir Products and Chemicals, Inc.
InventorsJeremiah P. Casey, Susan M. Clift
Life of this patent
Estimating the term…
Abstract
The present invention relates to a process for the production of polyurethanes wherein a tertiary amine functionality is incorporated into the side chain of a diaminobenzoate to form catalytic polyurethane chain extender. These chain extenders are polyurethane catalysts which provide adequate cure without residual odor and safety hazards associated with the more traditional tertiary amine catalysts. When reacted with the isocyanate reactive group the non-tertiary amine portion of the chain extender is bound to the polymeric network thereby preventing diffusion of the catalyst species from the polyurethane and negating odor and toxicity as problems. The diaminobenzoate provides enhanced polyurethane physical properties.
Claims4
In a process for the preparation of a polyurethane composition by reacting a polyisocyanate with a polyol, a chain extender and a catalyst, the improvement which comprises reacting a catalytic chain extender comprising a diaminobenzoate having a tertiary amine functionality incorporated into a side chain of the diaminobenzoate.
A polyurethane composition obtained by reacting a polyisocyanate, a polyol and a catalytic chain extender wherein the catalytic chain extender comprises a diaminobenzoate having a tertiary amine functionality incorporated into a side chain of the diaminobenzoate represented by the general formula:
- ##STR15## wherein:
- Y= ##STR16## and R.sub.1 =(CH.sub.2).sub.n, n=2-5
- R.sub.2, R.sub.3, =C.sub.1-4 alkyl or C.sub.2-6 alkoxyalkyl
- R.sub.4 =C.sub.3-9 alkyl and
- R.sub.5 =C.sub.1-4 alkyl.
Dependencies are inferred from the claim text.