Water-in-oil type emulsion explosive with chelating agent
AssigneeNippon Oil and Fats Co., Ltd.
InventorsTomoyuki Amano, Koichi Kurokawa, Koji Edamura
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Abstract
Thermostability, age stability, and ignition property at low temperatures of a W/O type emulsion explosive are remarkably improved by incorporating a chelating agent in the W/O type emulsion explosive.
Claims3
A water in oil type emulsion explosive composed of a continuous phase consisting of a carbonaceous fuel, a dispersive phase consisting of an aqueous solution of an inorganic oxidative salt, an emulsifier, an auxiliary sensitizer, and a foam retainer, comprising further at least one chelating agent selected from the group consisting of tartaric acid, oxalic acid, ethylenediaminetetraacetic acid, and alkali metal salts and alkaline earth metal salts thereof;
- nitrilotriacetic acid, thioglycolic acid, ascorbic acid, sulfosalicyclic acid, and alkali metal salts thereof;
- triethanolamine, ethylenediamine, triethylenetetramine, acetylacetone, dihydroxyethylglycine, thiourea, diethyldithiocarbamine, diaminobenzene, 2,3-dimercapto propanol, o-phenanthoroline, and pyrocatechol-3,5-disulfonate;
- in an amount of 0.1-10 wt % relative to the amount of the auxiliary sensitizer, said auxiliary sensitizer being a nitric acid salt of a compound of the general formula
- X--NH.sub.2
- wherein X represents CH.sub.3 CONH.sub.2,CH.sub.2 CH.sub.2 NH.sub.2,CH.sub.2 CH.sub.2 OH, NH.sub.2 or H.sub.2 NCNH and in an amount of 0.5-50 wt % in the emulsion.
Dependencies are inferred from the claim text.