Blends of polar thermoplastic polymers and modified block copolymers
AssigneeShell Oil Company
InventorMichael J. Modic
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Abstract
A multiphase thermoplastic composition is provided by incorporating at least one polar thermoplastic polymer with at least one functionalized, selectively hydrogenated alkenyl arene/conjugated diene block copolymer to which has been grafted an effective amount of carboxyl functional groups primarily in the alkenyl arene blocks thereof. The carboxyl functional groups may be in the form of carboxylic acids, their salts and esters, and combinations thereof. The rubbery compositions of the present invention possess improved tensile strength, high temperature mechanical properties and oil resistance.
Claims57
A multiphase thermoplastic composition comprising:
- (a) one phase containing at least one polar thermoplastic polymer each containing at least one polar functional group;
- and
- (b) at least one other phase containing at least one functionalized, selectively hydrogenated block copolymer to which has been grafted on the average an effective amount of carboxyl functional groups for imparting improved tensile strength, high temperature mechanical properties and oil resistance to said multiphase thermoplastic composition, said functionalized block copolymer comprising
- (1) a base block copolymer which comprises
- (i) at least one polymer block A, said A block being predominantly a polymerized alkenyl arene block, and
- (ii) at least one selectively hydrogenated polymer block B, said B block prior to hydrogenation being predominantly a polymerized conjugated diene block,
- (2) wherein substantially all of said carboxyl functional groups are grafted to said base block copolymer on said A blocks,
- (c) said one phase (a) being present in a weight ratio of about 1:99 up to less than about 50:50 relative to said at least one other phase (b), and
- (d) said polar thermoplastic polymer excluding said functionalized block copolymer.
Dependencies are inferred from the claim text.