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AssigneeHitachi, Ltd.
InventorsHisao Yamashita, Akira Kato, Shigeo Uno, Mamoru Mizumoto, Shinpei Matsuda
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The disclosure is concerned with a high temperature stable catalyst comprising an alumina base support and a catalytically active component supported on the support. The support is featured by its specific composite oxide having a specific surface area of at least 10 m.sup.2 /g and a structural form of amorphous state or a phase resemble to lanthanoide .beta.-alumina. The composite oxide can be converted to lanthanoide .beta.-alumina when heated to an elevated temperature above 1000.degree. C. within 2 hours. The composite oxide is substantially free from such ingredients as accelerate grain growth of alumina. The ingredients are for example Cr, Sr or Ce. The present dislcosure is also concerned with a process for preparing the catalyst and a process for conducting chemical reactions such as steam reforming, desulfurization of heavy oil, cracking of hydrocarbons, etc. using the catalyst.
A process for conducting a catalytic oxidation reaction, which comprises contacting fluid fuel and an oxidant with a catalyst comprising a support and a catalytically active component supported on aid support, wherein at least the part of said support that predominantly supports said active component consists essentially of a composite oxide of aluminum and at least one member selected from the group consisting of lanthanum, neodymium, praseodymium and mixtures thereof, said composite oxide having a specific surface area of at least 10 m.sup.2 /g, and being characterized in that it exhibits characteristic peaks corresponding to those of lanthanide-beta -alumina in X-ray diffraction analysis.
A process for conducting a catalytic oxidation reaction according to claim 20, wherein the composite oxide has a composition of 3 to 10 molar % of the oxide of at least one member selected from the group consisting of lanthanum, neodymium, and praseodymium and the balance being alumina
A process for conducting a catalytic oxidation reaction, which comprises contacting fluid fuel and an oxidant with a catalyst comprising a support and a catalytically active component supported on said support, wherein at least the part of said support that predominantly supports said active component consists essentially of a composite oxide of alumina and at least one member consisting of the group consisting of lanthanum, neodymium, praseodymium and mixtures thereof, said composite oxide having a specific surface area of at least 10 m.sup.2 /g, said composite oxide containing less than 1% by weight of chromium, strontium and cerium, and said composite oxide being characterized in that it exhibits characteristic peaks corresponding to those of lanthanide-beta-alumina in the X-ray diffraction analysis and said composite oxide being a calcination product of a mixture of an aluminum compound and a member selected from the group consisting of lanthanum compound, neodymium compound, praseodymium compound and mixtures thereof calcined at a temperature of at least 800.degree. C. for time sufficient to convert the mixture into said composite oxide.
Dependencies are inferred from the claim text.