Alkaline earth metal spinel/kaolin clays and processes for making
AssigneeUop LLC
InventorAlakanada Bhattacharyya
Life of this patent
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Abstract
A process for the production of an alkaline earth metal, aluminum-containing spinel/clay composition comprises: (a) combining (1) an acidic, aluminum-containing composition in which the aluminum is present in a positively charged species, and (2) a basic, alkaline earth metal-containing composition to form a gel mixture; (b) mixing the gel with kaolin clay to form a co-gel; and (c) calcining the co-gel mixture to form the alkaline earth metal, aluminum-containing spinel composition in a clay matrix. Alkaline earth metal, aluminum-containing spinel/clays having both high surface areas and very high attrition resistance, and processes for using spinel/clay compositions, e.g., as sulfur oxide and nitrogen oxide removal agent, are also disclosed.
Claims74
A process for the production of an alkaline earth metal, aluminum-containing spinel/kaolin clay composition comprising:
- (a) combining (1) an acidic, aluminum-containing composition in which the aluminum is present in a positively charged species, (2) a basic alkaline earth metal-containing composition to form a gel mixture;
- and
- (b) mixing the gel with kaolin clay to form a co-gel mixture;
- and
- (c) calcining said co-gel mixture to form said alkaline earth metal, aluminum-containing spinel composition, in a kaolin clay matrix.
A process for the production of alkaline earth metal, aluminum-containing spinel/kaolin clay compositions comprising:
- (a) combining (1) an acidic, aluminum-containing composition in which the aluminum is present in a positively charged species;
- (2) a basic, alkaline earth metal-containing composition to form a co-gel mixture;
- (b) optionally, mixing the co-gel mixture with additional kaolin clay;
- and
- (c) calcining said co-gel mixture to form said alkaline earth metal, aluminum-containing spinel composition in a kaolin clay matrix.
An alkaline earth metal, aluminum-spinel/clay composition wherein said spinel has a surface area greater than about 40 m.sup.2 /gm. and an attrition resistance index less than about 3.0.
Dependencies are inferred from the claim text.