US 4,903,767 AGranted

Selective gelation polymer for profile control in CO.sub.2 flooding

AssigneeMobil Oil Corporation

InventorsPaul Shu, Krishnaswamy Sampath

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Abstract

A process for the selective gelation of a polymer for profile control during carbon dioxide flooding. First, a size selective gel is formed ex-situ. Upon entering a thief zone or a more permeable low pH zone resultant from carbon-dioxide flooding, the gel forms a solid, firm gel. This gel comprises an aqueous composition of a partially and fully alkylated melamine resin and an xanthan polymer. Size selectivity is imparted by the partially alkylated resin and the polymer. Upon contact with the low pH environment, active melamine resin is released from the fully alkylated resin which reacts with the polymer to form a stable, solid gel. Once the solid gel has formed, steam-flooding, water-flooding or a carbon-dioxide oil recovery process is commenced in a zone where a solid gel has not formed.

Claims39

Dependent claims

A method for closing at least one zone in a subterranean formation where a carbon dioxide flooding process has caused the existence of carbon dioxide break-through fingers comprising:

(a) introducing a gas selected from a member of the group consisting of carbon dioxide and gases containing carbon dioxide into a subterranean deposit containing carbon dioxide break-through fingers;
(b) after said carbon dioxide break-through fingers have sorbed a predetermined amount of said gas, stopping the flow of said gas into said subterranean formation;
(c) after stopping the flow of said gas into said subterranean formation, introducing an effective amount of a gel-forming composition into said subterranean formation and into said carbon dioxide break-through fingers, said gel-forming composition being operable, when contacting carbon dioxide break-through fingers containing an aqueous fluid which has absorbed substantial amounts of carbon dioxide, to form a gel in said fingers which is operable for retarding the flow of said gas through said fingers, said gel-forming composition comprising
(i) an aqueous solution containing a water soluble xanthan polymer;
and
(ii) a partially and a fully alkylated melamine resin sufficient to cross-link said polymer;
(d) injecting selectively said gel-forming composition into the break-through fingers of said formation where selectively is imparted by a higher viscosity resultant from said partially alkylated resin;
and
(e) allowing said composition to remain in the formation for a time sufficient for the fully alkylated resin to form an active resin which results in the creation of a stable solid gel which closes said fingers.

6 more elements

A method for selectively closing carbon dioxide break-through fingers in a subterranean formation comprising:

(a) conducting a carbon dioxide oil recovery process in said formation until carbon dioxide break-through occurs during which process carbon dioxide is sorbed into aqueous formation fluids in an amount sufficient to create a substantially low pH environment of about 3 to about 5;
(b) ceasing said carbon dioxide oil recovery process;
(c) introducing thereafter an effective amount of a gel-forming composition into said subterranean formation and into said carbon dioxide break-through fingers, said gel-forming composition being operable, when contacting carbon dioxide break-through fingers containing said fluids with a substantially low pH, to form a gel in said fingers which is operable for retarding the flow of carbon dioxide through said fingers, said gel-forming composition comprising
(i) an aqueous solution containing a water soluble xanthan polymer, and
(ii) a partially and a fully alkylated melamine resin sufficient to cross-link said polymer;
(d) injecting selectively said gel-forming composition into the break-through fingers of said formation where selectively is imparted by a higher viscosity resultant from said partially alkylated resin;
(e) allowing said composition to remain in the formation for a time sufficient for the fully alkylated rresin to form an active resin thereby creating a stable solid gel which closes said fingers;
and
(f) conducting an enhanced oil recovery method in said formation and recovering hydrocarbonaceous fluids.

6 more elements

Dependencies are inferred from the claim text.