A process for the simultaneous hydrodehalogenation of a first feedstock comprising unsaturated, halogenated organic compounds and a second feedstock comprising saturated, halogenated organic compounds which process comprises:
- (a) contacting said first feedstock comprising unsaturated, halogenated organic compounds with a first dried hydrogen-rich gas stream in a first hydrogenation reaction zone operated at hydrogenation conditions selected to minimize the polymerization of unsaturated organic compounds and to produce a first hydrogenated stream comprising hydrocarbonaceous compounds;
- (b) reacting at least a portion of said first hydrogenated stream comprising hydrocarbonaceous compounds and said second feedstock comprising saturated, halogenated organic compounds with hydrogen in a second hydrogenation reaction zone operated at hydrogenation conditions selected to produce a second hydrogenated stream comprising hydrocarbonaceous compounds and to generate at least one water-soluble hydrogen halide compound;
- (c) containing said second hydrogenated stream with a halide-lean absorber solution in an absorption zone;
- (d) withdrawing a halide-rich absorber solution containing at least a portion of said water-soluble hydrogen halide compound from said absorption zone;
- (e) withdrawing a first stream comprising hydrogenated hydrocarbonaceous compounds and a hydrogen-rich gas from said absorption zone;
- (f) introducing said first stream recovered in step (e) into a separation zone to produce a hydrogen-rich gas stream comprising water vapor and a second stream comprising hydrogenated hydrocarbonaceous compounds;
- (g) removing at least a portion of said water vapor from said hydrogen-rich gas stream comprising water vapor in a drying zone to produce a second dried hydrogen-rich gas stream;
- and
- (h) recycling at least a portion of said second dried hydrogen-rich gas stream to step (a) as said first dried hydrogen-rich gas stream.