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US 4,902,768 AGranted
Elastomers prepared from N-(polyoxyalkyl)-N-(alkyl)amines
AssigneeUnion Carbide Chemicals and Plastics Company Inc.
InventorsRichard M. Gerkin, Nigel Barksby
Life of this patent
Estimating the term…
Abstract
N-(polyoxyalkyl)-N-(alkyl)amines are reacted with isocyanates and chain extenders to form polyureas and/or polyurethane-urea elastomers.
Claims26
A process for the preparation of elastomers which process comprises:
- reacting a amine mixture with an isocyanate in the presence of a chain extender wherein the amine mixture is of the general formula:
- ##STR8## wherein:
- R represents an initiator radical based on a compound containing Zerewitinoff active hydrogen atoms;
- H represents a hydroxy-containing group of the formula:
- ##STR9## P represents a primary amine-containing group of the formula:
- ##STR10## S represents a secondary amine-containing group of the formula:
- ##STR11## T represents a tertiary amine-containing group of the formula:
- ##STR12## a is 0 to I75;
- b is 0 to 175;
- c is 0 to 30;
- n is 1 to 3;
- the sum a+b+c must be greater than or equal to 2 when, n equals 1;
- R' is an alkyl group containing from two carbon atom to eighteen carbon atoms;
- R" is hydrogen or an alkyl group containing up to eighteen carbon atoms;
- R'" and R"" are independently alkyl groups containing from two to twelve carbon atoms;
- h is from 0 to 0.7;
- p is from 0 to 0.5;
- s is from 0.5 to 1.0;
- t is from 0 to 0.15;
- (hz) is the product of h and z;
- p+s+t=1;
- and
- z is 2 to 6, with the proviso that when z is 2 and a is zero, then b must be greater than 22.
20 more elements
A process for the preparation of polyurea elastomers of polyurethane-urea elastomers which process comprises:
- reacting a amine mixture with an isocyanate in the presence of a chain extender wherein the amine mixture is of the general formula:
- ##STR14## wherein:
- R represents an initiator radical based on a compound containing Zerewitinoff active hydrogen atoms;
- H represents a hydroxy-containing group of the formula:
- ##STR15## P represents a primary amino-containing group of the formula:
- ##STR16## S represents a secondary amine-containing group of the formula:
- ##STR17## T represents a tertiary amine-containing group of the formula:
- ##STR18## a is 0 to 175;
- b is 0 to 175;
- c is 0 to 30;
- n is 1 to 3;
- the sum a+b+c must be greater than or equal to 2 when n equals 1;
- R' is an alkyl group containing from two carbon atoms to eighteen carbon atoms;
- R" is hydrogen or an alkyl group containing up to eighteen carbon atoms;
- R'" and R"" independently alkyl groups containing from two to twelve carbon atoms;
- h is from 0 to 0.3;
- p is from 0 to 0.4;
- s is from 0.7 to 1.0;
- t is from 0 to 0.05;
- (hz) is the product of h and z;
- p+s+t=1;
- z is 3 to 6;
- and
- where the equivalent weight of the amine is from about 1,000 to 10,000.
21 more elements
Dependencies are inferred from the claim text.