Preparation of modified acrylamide polymers
AssigneeAmerican Cyanamid Company
InventorsMorris E. Lewellyn, Donald P. Spitzer
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Abstract
A process for the preparation of hydroxamated polymers of acrylamide is disclosed whereby the polymer is reacted with a hydroxylamine salt at pH of at least about 8.0.
Claims3
In a process for the preparation of an acrylamide polymer containing hydroxamic groups by reacting an aqueous solution of an acrylamide polymer with a hydroxylamine salt at a mole ratio of hydroxylamine to amide groups in the acrylamide polymer of from about 0.1 to about 2.0, the improvement which comprises conducting the reaction at a pH of at least about 11.0, a temperature ranging from about 40.degree.-80.degree. C., for from about 1-4 hours and at a polymer solution concentration of at least 2%, by weight, the polymer having a molecular weight of from about 10.sup.6 to about 3.times.10.sup.7, said pH being that naturally occurring after substantially complete neutralization of said hydroxylamine salt.
Dependencies are inferred from the claim text.