Thermoplastic polyolefin composite structure
AssigneeE. I. Du Pont de Nemours and Company
InventorFrank Rohrbacher
Life of this patent
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Abstract
A thermoplastic polyolefin composite that is useful as an exterior auto or truck body part has the following layers of components: a. a layer of a glossy clear thermoplastic finish bonded firmly to b. a layer of a thermoplastic pigment containing paint firmly bonded to c. a thin size layer of a thermoplastic chlorinated polyolefin that is firmly bonded to d. a flexible sheet of a thermoplastic polyolefin resin. A thermoformable composite sheet structure that can be made into the above laminate having the layers a.-d. of the above structure also is part of this invention.
Claims25
A three dimensional thermoplastic polyolefin composite useful as an exterior auto or truck body part consisting essentially of the following components:
- 1. a multilayer coating consisting essentially of
- a. a 10-125 micron thick layer of a glossy clear thermoplastic finish formed from a clear coating composition bonded firmly to
- b. a 5-75 micron thick layer of a thermoplastic pigment containing paint firmly bonded to
- c. a 1-25 micron thick size layer of a thermoplastic chlorinated polyolefin containing 15-50% by weight chlorine;
- said multilayer coating formed by applying a layer of a clear coating composition to a polymeric film, applying a paint layer to the layer of clear coating composition and then applying a layer of the thermoplastic chlorinated polyolefin to the paint layer and curing the multilayer coating;
- said multilayer being firmly bonded by lamination to
- 2. a 250-1250 micron thick layer of a flexible extruded sheet of a thermoplastic polyolefin having a flexural modulus of about 175-2100 MPa and a melt flow rate of about 0.5-2.0 g/10 min.;
- wherein the chlorinated polyolefin layer of the multilayer coating is in contact with the sheet of thermoplastic polyolefin and the polymeric sheet is removed after lamination to leave a smooth glossy surface on the clear layer and the resulting flexible sheet having the multilayer coating is thermoformed into a three dimensional structure that is bonded to
- 3. a 500-25,000 micron thick rigid layer of a thermoplastic polyolefin resin having a modulus of about 175-2100 MPa and a melt flow rate of about 4.0-8.0 g/10 min. formed by injection molding said resin to the flexible sheet having a three dimensional structure;
- wherein layers a. and b. of the multilayer form the exterior surface of the composite and have a gloss of at least 60 measured at 20.degree. and a distinctness of image of at least 60.
Dependencies are inferred from the claim text.