Process for producing an acrylic fiber having high fiber characteristics

A process for producing an acrylic fiber having a strength of at least 10 g/d, a modulus of at least 180 g/d, at least 95% X-ray orientation, and X-ray crystallinity parameter of up to 0.8 degree and a knot strength of at least 4 g/d, comprising the steps of:

• (a) producing a polymer having a weight-average molecular weight of at least 5.times.10.sup.5 wherein a mixture of 10-70 wt % of a polymerizable unsaturated monomer mixture containing acrylonitrile of at least 80%, 15-60 wt % of an organic solvent selected from dimethylformamide, dimethylacetamide, .gamma.-butyrolactone or dimethylsulfoxide and 15-60 wt % of water is polymerized in the presence of a radical initiator and further polymerized with at least one of said water and organic solvent in a total amount of 1-10 parts by weight per part by weight of the charge polymerizable monomer,
• (b) dissolving said polymer in a spinning solution comprising water and dimethylformamide or dimethylacetamide at a polymer concentration of 15-50 wt % to provide the spinning solution having a viscosity of 500-1,500 poises at 45.degree. C., wherein the concentrations of said water and polymer in the spinning solution using dimethylformamide as a spinning solvent are within amounts defined by an area bounded by straight lines connecting points A, D and C which have coordinates of (1, 15), (1, 5) and (10, 5), respectively, or wherein the concentration of said water and polymer on the spinning solution using dimethylacetamide as a spinning solvent are within amounts defined by an area bounded by straight lines connecting points A', B' and C' which have coordinates of (1, 15), (1, 5) and (5, 5), respectively, on a rectangular coordinates system in which the water concentration is plotted on the x-axis and the polymer concentration is plotted on the y-axis,
• (c) extruding the spinning solution into a gaseous medium to form filaments;
• (d) introducing the filaments into a coagulation bath comprising water and at least one of dimethylformamide and dimethylacetamide at 0.degree. C. or below;
• and
• (e) stretching the coagulated filaments to draw a ratio of at least 10.