Process for removal of soluble platinum group metal catalysts from liquid product mixtures
AssigneeGAF Chemicals Corporation
InventorsBasil A. Behnam, Rastko Vukov
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AssigneeGAF Chemicals Corporation
InventorsBasil A. Behnam, Rastko Vukov
Estimating the term…
A process for the neutralization, clarification and decolorization of organosilanes or organosilicones derived from the reaction of an organosilane or a hydropolysiloxane with an aliphatically unsaturated compound in the presence of an acidic platinum catalyst, a process for the conversion of a soluble platinum catalyst into an insoluble form and a process for the recovery of a platinum catalyst from an insoluble anion exchange resin which comprises: (a) contacting a reaction mixture of the organosilane or organosilicone with a basic anionic exchange resin having a free amino or quaternized ammonium salt functionality in an insoluble polymeric matrix under conditions suitable to bind the soluble platinum catalyst to said resin; (b) separating said resin containing bound platinum catalyst from the organosilane or organosilicone reaction mixture and, optionally, (c) treating the separated resin with an inorganic base to convert the bound platinum catalyst to a recoverable salt or (d) subjecting the resin containing bound platinum catalyst to combustion to recover elemental platinum.
The process for removing a platinum group metal compound from a liquid product mixture containing from about 1 to about 5,000 ppm of an acidic platinum group metal compound which comprises (a) contacting and agitating said liquid with basic macroreticular anionic exchange resin particles having a particle size of from about 60 to about 1,000 mesh, a moisture content less than 15% and an ion exchange capacity of from about 0.5 to about 40 meq/ml for a period and at a temperature sufficient to react said acidic platinum metal group compound with said ion exchange resin and (b) separating a clear colorless liquid product from said reacted ion exchange resin particles.
Dependencies are inferred from the claim text.