Magnetic recording medium
AssigneeTDK Corporation
InventorsKenji Yokoyama, Masatoshi Nakayama, Toru Shimozawa, Kunihiro Ueda, Fumio Maruta
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Abstract
In a magnetic recording medium wherein a metal thin film magnetic layer and an overcoat are formed on a nonmagnetic substrate, durability is improved when the overcoat comprises a plasma-polymerized film and a topcoat of an organic fluorine compound; a plasma-polymerized film, a protective carbon film, and a topcoat of an organic fluorine compound; a plasma-polymerized film containing C, F and H; or a plasma-polymerized organometallic film and a fluorine or silicon-containing topcoat. Oxidation of the upper surface of the magnetic layer with a plasma is also effective.
Claims10
A magnetic recording medium comprising a nonmagnetic rigid substrate having opposed major surfaces,
- a metal thin film magnetic layer disposed on one major surface of the substrate, and
- a topcoat layer on the magnetic layer, said topcoat layer comprising a plasma-polymerized film containing carbon, fluorine, wherein the carbon content ranges from 30 to 80 atom %, the hydrogen-to fluorine atom ratio ranges from 0.1.0 to 1.0:1.0, and the average fluorine-to-carbon atom ratio (F/C) in the region of said film that extends from the surface remote from the substrate to 1/3rd of its thickness is at least 1.5 times that in the region of the film that extends from the surface adjacent to the substrate to 1/3rd of its thickness, said plasma-polymerized film being prepared by activating a gaseous reactant into a plasma to generate active species thereof while feeding the reactant into a plasma zone with W/F.M set to 10.sup.7 to 10.sup.15 joule/kg, wherein W is an input power applied for plasma generation, F is the flow rate of the gas reactant, and M is the molecular weight of the gas reactant, whereby the polymerized film has a thickness of 3 to 800 .ANG. and a contact angle with water in the range of from 100.degree. to 130.degree..
Dependencies are inferred from the claim text.