Electrorefining process and apparatus for recovery of uranium and a mixture of uranium and plutonium from spent fuels

A process for refining spent nuclear fuel containing uranium and plutonium, comprising the steps of:

• providing an electrolytic cell having a lower molten cadmium pool containing spent nuclear fuel, an intermediate molten electrolyte pool containing mixed metal chloride salts floating on said lower molten cadmium pool, an anode basket containing spent nuclear fuel, a first and second cathode, said first cathode composed of a solid alloy and said second cathode composed of molten cadmium, and electrical power means connected to said molten cadmium pool, said anode basket and said cathodes for providing electrical power to the cell,
• dissolving additional amounts of uranium and plutonium from said anode basket in said molten cadmium pool,
• extending said first cathode into said intermediate molten electrolyte pool,
• electrolytically depositing uranium on said first cathode,
• retracting said first cathode from said intermediate molten electrolyte pool,
• subsequently extending said second molten cadmium cathode into said intermediate electrolyte pool,
• electrolytically depositing a mixture of uranium and plutonium on said second molten cadmium cathode, and
• retracting said second molten cadmium cathode from said intermediate molten electrolyte.

A process for refining spent nuclear fuel containing uranium and plutonium, comprising the steps of:

• providing an electrolytic cell having a lower molten cadmium pool containing spent nuclear fuel, an intermediate molten electrolyte pool containing mixed metal chloride salts floating on said lower molten cadmium pool, an anode basket containing spent nuclear fuel, two molten cadmium cathodes, and electrical power means connected to said molten cadmium pool, said anode basket and said cathodes for providing electrical power to the cell,
• dissolving additional amounts of uranium and plutonium in said lower molten cadmium pool,
• saturating said lower molten cadmium pool with uranium, but not with plutonium,
• extending a first molten cadmium cathode into said intermediate molten electrolyte pool,
• electrolytically transporting and depositing uranium on said first cathode until said lower molten cadmium pool is no longer saturated with uranium,
• extending a second molten cadmium cathode into said intermediate molten electrolyte pool,
• electrolytically transporting and depositing a mixture of uranium and plutonium on said second cathode,
• retracting said first and second cathodes from said intermediate molten electrolyte pool, and
• vaporizing said cadmium to provide purified uranium and uranium-plutonium products.

An electrolytic cell for recovering U and a mixture of U and Pu from spent nuclear fuel comprising:

• a metallic pot including forming a lower zone for retaining a lower molten cadmium pool containing spent nuclear fuel and an intermediate zone for retaining a molten electrolyte salt floating on said molten cadmium pool,
• electrode means including at least one anode basket containing spent nuclear fuel, a first solid cathode for collecting U and a second molten cadmium cathode for subsequently collecting a mixture of U and Pu,
• means for extending said anode basket into the intermediate and lower zones and said cathodes into the intermediate zone, and means for retracting said anode basket and said cathodes from said intermediate and lower zones to an area above said zones, and
• electrical power means connected to said anode basket, said cathodes and said molten cadmium pool for providing electrical power to the cell.

An electrolytic cell for recovering U and a mixture of U and Pu from spent nuclear fuel comprising:

• a metallic pot including forming a lower zone for retaining a lower molten cadmium pool containing spent nuclear fuel and an intermediate zone for retaining a molten electrolyte salt floating on said molten cadmium pool,
• electrode means including at least one anode basket containing spent nuclear fuel, a first molten cadmium cathode for collecting U and a second molten cadmium cathode for subsequently collecting a mixture of U and Pu,
• means for extending said anode basket into the intermediate and lower zones and said cathodes into the intermediate zone, and means for retracting said anode basket and cathodes from said intermediate and lower zones to an area above said zones, and
• electrical power means connected to said anode basket, said cathodes and said molten cadmium pool for providing electrical power to the cell.