Method of and apparatus for measuring vapor density

In an apparatus for measuring the concentration of individual components of a multi-component system, said apparatus being in the form of a hygrometer including means for transmitting an electromagnetic radiation input signal through a sample that has at least one of said system components therein, wherein said system includes water vapor as one of the individual components, said electromagnetic radiation input signal being within a broad wavelength band that includes a given wavelength selected for strong absorption by the water vapor in said sample;

• the improvement comprising:
• means responsive to said electromagnetic radiation input signal after transmission thereof through said sample for generating an output signal indicative of the concentration of said one component in said sample, said generating means including means fabricated from indium arsenide and being linearly responsive to said transmitted electromagnetic radiation input signal at said given wavelength and over a relatively wide portion of said wavelength band of said input signal for generating said output signal;
• said transmitting means including means for producing said electromagnetic radiation input signal in temporally spaced pulses, wherein one of said pulses has said given wavelength, and others of said pulses temporally precede and follow said one pulse and have a second wavelength selected for weak absorption by water vapor;
• and
• said indium arsenide means having a linear response to said electromagnetic radiation input signal at said given and second wavelengths over said relatively wide portion of said wavelength band of said input signal.

In an apparatus for measuring the concentration of individual components of a multicomponent system, including means for transmitting an electromagnetic radiation input signal through a sample that has at least one of said system components therein, said electromagnetic radiation input signal being within a broad wavelength band that includes a given wavelength selected for strong absorption by said one component in said sample;

• the improvement comprising;
• means responsive to said electromagnetic radiation input signal after transmission thereof through said sample for generating an output signal indicative of the concentration of said one component in said sample, said generating means including photovoltaic means responsive to said transmitted electromagnetic radiation input signal at said given wavelength and linearly over a relatively wide range of input signal intensities for generating said output signal;
• said transmitting means including means for producing said electromagnetic radiation input signal in temporally spaced pulses, wherein one of said pulses has said given wavelength, and others of said pulses temporally precede and follow said one pulse and have a second wavelength selected for weak absorption by said one component;
• said photovoltaic means including an indium arsenide electromagnetic radiation detector having a linear response to said electromagnetic radiation input signal at said given and second wavelengths over a relatively wide range of intensity of said input signal;
• and
• said generating means generates said output signal based on the value of:
• ##EQU11## where N1 is proportional to the transmission of one of said other pulses through said sample, N2 is proportional to the transmission of said one pulse through said sample, N3 is proportional to the transmission of another of said other pulses through said sample and said other pulses are temporally equally spaced from said one pulse.

In an apparatus for measuring the concentration of individual components of a multicomponent system, including means for transmitting an electromagnetic radiation input signal through a sample that has at least one of said system components therein, said electromagnetic radiation input signal being within a broad wavelength band that includes a given wavelength selected for strong absorption by said one component in said sample;

• the improvement comprising;
• means responsive to said electromagnetic radiation input signal after transmission thereof through said sample for generating an output signal indicative of the concentration of said one component in said sample, said generating means including photovoltaic means responsive to said transmitted electromagnetic radiation input signal at said given wavelength and linearly over a relatively wide range of input signal intensities for generating said output signal;
• said transmitting means including means for producing said electromagnetic radiation input signal in temporally spaced pulses, wherein one of said pulses has said given wavelength, and others of said pulses temporally precede and follow said one pulse and have a second wavelength selected for weak absorption by said one component;
• said photovoltaic means including an indium arsenide electromagnetic radiation detector having a linear response to said electromagnetic radiation input signal at said given and second wavelengths over a relatively wide range of intensity of said input signal;
• and
• said photovoltaic means generates a signal N1 proportional to the transmission of one of said other pulses through said sample, a signal N2 proportional to the transmission of said one pulse through said sample, and a signal N3 proportional to the transmission of another of said other pulses through said sample;
• and
• said generating means generates said output signal based on the value of said signal N2 divided by the interpolated value of said N1 and N2 signals at the time of said N2 signal, said generating means being effective to obtain said interpolated value by interpolation using said N1 and N2 signals.

In an apparatus for measuring the concentration of individual components of a multicomponent system, including means for transmitting an electromagnetic radiation input signal through a sample that has at least one of said system components therein, said electromagnetic radiation input signal being within a broad wavelength band that includes a given wavelength selected for strong absorption of said one component in said sample;

• wherein a background electromagnetic signal is also detected by said photovoltaic means, the further improvement comprising:
• means responsive to said electromagnetic radiation input signal after transmission thereof through said sample for generating an output signal indicative of the concentration of said one component in said sample, said generating means including photovoltaic means responsive to said transmitted electromagnetic radiation input signal at said given wavelength and linearly over a relatively wide range of input signal intensities for generating said output signal;
• said transmitting means including means for producing said electromagnetic radiation input signal in temporally spaced pulses, wherein one of said pulses has said given wavelength, and others of said pulses temporally precede and follow said one pulse and have a second wavelength selected for weak absorption by said one component;
• said photovoltaic means being responsive to said one and other pulses and to said background signal for respectively generating detector signals, wherein a detector signal N1A is the detector signal at time interval A and at said second wavelength, a detector signal N2B is the detector signal at time interval B and at said given wavelength, a detector signal NBC is the detector signal at time interval C and in response to said background signal, and a detector signal N1D is the detector signal N at time D and at said second wavelength;
• and
• said generating means generates said output signal based on the value of:
• ##EQU12## where K1A and K1D sum to 1.00 and are chosen to yield a time-weighted average of said signals N1A and N1D that is applicable at said time interval B.

In an apparatus for measuring the concentration of individual components of a multi-component system, said apparatus including means for transmitting an electromagnetic radiation input signal through a sample that has at least carbon dioxide or methane or water vapor as one of said system components therein, said signal being within a detector response wavelength band that includes a given wavelength selected for strong absorption by said one component in said sample;

• the improvement comprising;
• said transmitting means including means for producing said electromagnetic radiation input signal in temporally spaced pulses, wherein one pulse having said given wavelength is preceded and followed by respective temporally preceding and temporally following pulses having a second wavelength in said detector response band, said second wavelength being selected for weak absorption by said one component;
• means including a detector fabricated from indium arsenide for sensing electromagnetic radiation, said detector being responsive to said electromagnetic radiation input signal upon the exiting thereof from said sample and at said given wavelength for generating a series of output signals having a value that varies linearly with respect to the intensity of said electromagnetic radiation pulses at said given and second wavelengths transmitted through said sample, said linearity being over an operating range of from 1 to 3.8 microns, where said given and second wavelengths are in said operating range;
• and
• means are responsive to said series of output signals for producing a concentration measurement signal based on the value of:
• ##EQU13## where N1 is the total value over time of a first output signal corresponding to said temporally preceding pulse, N2 is the total value over time of a second output signal corresponding to said one pulse having said given wavelength, N3 is the total value over time of a third output signal corresponding to said temporally following pulse and said first and third output signals are temporally equally spaced from said second output signal.

In an apparatus for measuring the concentration of individual components of a multi-component system, said apparatus including means for transmitting an electromagnetic radiation input signal through a sample that has at least carbon dioxide or methane or water vapor as one of said system components therein, said signal being within a detector response wavelength band that includes a given wavelength selected for strong absorption by said one component in said sample;

• the improvement comprising:
• said transmitting means including means for producing said electromagnetic radiation input signal in temporally spaced pulses, wherein one pulse having said given wavelength is preceded and followed by respective temporally preceding and temporally following pulses having a second wavelength in said detector response band, said second wavelength being selected for weak absorption by said one component;
• photovoltaic means including a detector fabricated from indium arsenide for sensing electromagnetic radiation, said detector being responsive to said electromagnetic radiation input signal pulses upon the exiting thereof from said sample and at said given and second wavelengths for generating a series of output signals having values linear with regard to the intensity of said electromagnetic radiation at said given and second wavelengths transmitted through said sample;
• said detector having said linear response to said pulses at said given and second wavelengths over the intensity range of said pulses;
• said detector is also responsive to background electromagnetic radiation transmitted through said sample for generating a reference signal NB that shifts the reference level of said output signals;
• and
• means to said series of output signals for producing said concentration measurement signal based on the value of:
• ##EQU14## where N1 is the total value over time of a first output signal corresponding to said temporally preceding pulse, N2 is the total value over time of a second output signal corresponding to said one pulse having said given wavelength, N3 is the total value over time of a third output signal corresponding to said temporally following pulse, and K1 and K3 sum to 1.00 and are chosen to yield a time-weighted average of said signals N1 and N3 that is applicable at the time of the second output signal.

In a hygrometer including means for transmitting an infrared signal through a sample that has a water vapor content to be determined, said infrared signal being within a detector response band that includes a given wavelength selected for strong absorption by water vapor in said sample;

• the improvement comprising:
• said transmitting means including means for producing said infrared signal in the form of a series of pulses, wherein one of such pulses is at said given wavelength and others of said pulses temporally precede and follow said one such pulse and are at a second wavelength, said second wavelength being selected for weak water vapor absorption;
• means including a detector fabricated from indium arsenide, said detector being responsive to said pulses upon exiting thereof from said sample for generating a series of output signals having a value that varies linearly with respect to the intensity of said exiting pulses at said given and second wavelengths;
• said detector having said linear response to said pulses at said given and second wavelengths with respect to the intensity of said pulses over a relatively wide range of intensities of said pulses;
• and
• means responsive to said series of output signals for producing a water vapor content signal based on the value of:
• ##EQU15## where N1 is the total value over time of one of said output signals corresponding to said one of said preceding and following infrared pulses emitted from said sample, N2 is the total value over time of another of said output signals corresponding to said one infrared pulse at said given wavelength, N3 is the total value over time of another of said output signals corresponding to the other of said preceding and following infrared pulses at said second wavelength, and said preceding and following infrared pulses are temporally equally spaced from said one infrared pulse.

In a hygrometer including means for transmitting an infrared signal through a sample that has a water vapor content to be determined, said infrared signal being within a detector response band that includes a given wavelength selected for strong absorption by water vapor in said sample;

• the improvement comprising:
• said transmitting means including means for producing said infrared signal in the form of a series of pulses, wherein one of such pulses is at said given wavelength and others of said pulses temporally precede and follow said one such pulse and are at a second wavelength, said second wavelength being selected for weak water vapor absorption;
• means including a detector fabricated from indium arsenide, said detector being responsive to said pulses upon exiting thereof from said sample for generating a series of output signals having a value that varies linearly with respect to the intensity of said exiting pulses at said given and second wavelengths;
• said detector having said linear response to said pulses at said given and second wavelengths with respect to the intensity of said pulses over a relatively wide range of intensities of said pulses;
• and
• said detector is responsive to background electromagnetic radiation transmitted through said sample for generating a reference signal NB that shifts the reference level of said output signals;
• and
• means responsive to said series of output signals for producing a water vapor content signal based on the value of:
• ##EQU16## where N1 is the total value over time of one of said output signals corresponding to said one of said preceding and following infrared pulses emitted from said sample, N2 is the total value over time of another of said output signals corresponding to said one infrared pulse at said given wavelength, N3 is the total value over time of another of said output signals corresponding to the other of said preceding and following infrared pulses at said second wavelength, and K1 and K3 sum to 1.00 and are chosen to yield a time-weighted average of said signals N1 and N3 that is applicable at the time of the second output signal corresponding to said one infrared pulse.

In a hygrometer including means for transmitting an infrared signal through a sample that has a water vapor content to be determined, said infrared signal being within a detector response band that includes a given wavelength selected for strong absorption by water vapor in said sample;

• the improvement comprising:
• said transmitting means including means for producing infrared signal in the form of a series of pulses, wherein one of such pulses is at said given wavelength and others of said pulses temporally precede and follow said one such pulse and are at a second wavelength, said second wavelength being selected for weak water vapor absorption;
• means including a detector fabricated from indium arsenide, said detector being responsive to said infrared signal upon exiting thereof from said sample for generating a series of output signals having a value that varies linearly with respect to the intensity of said exiting signal at said given wavelength;
• said detector having said linear response to said pulses at said given and second wavelengths with respect to the intensity of said pulses over a relatively wide range of intensities of said pulses;
• said series of output signals generated by said detector including a signal N1 proportional to the transmission of one of said other pulses through said sample, a signal N2 proportional to the transmission of said one pulse through said sample, and a signal N3 proportional to the transmission of another of said other pulses through said sample;
• and
• means for producing a signal to indicate the water vapor concentration in said sample, said water vapor signal being based on the value of said signal N2 divided by the interpolated value of said N1 and N2 signals at the time of said N2 signal, said producing means being effective to obtain said interpolated value by interpolation using said N1 and N2 signals.

Apparatus for measuring the concentration of individual components of a multi-component system, including:

• means for producing a broadband electromagnetic radiation input signal that includes a selected strongly absorbing band for one of said components therein and a selected weakly absorbing region for said one of said components;
• means for selecting from said broadband input signal a series of electromagnetic radiation signals, said signals in said series including a first signal having a wavelength in said weakly absorbing region, a second signal having a wavelength in said strongly absorbing band and temporally spaced from said first signal, and a third signal having a wavelength in said weakly absorbing region and temporally spaced from said first and second signals, wherein said first, second and third signals are in a selected temporal order with said first and third signals temporally equally spaced from said second signal, said first, second and third signals being transmitted in a given path across a volume of said multi-component system;
• a sensor fabricated from indium arsenide and being linearly responsive to the intensity of said first, second, and third selected signals upon exiting thereof from said multi-component system for generating respective first, second, and third outputs having respective total values N1, N2, and N3 over time proportional to the intensity of said respective first, second, and third signals transmitted through said multi-component system;
• and
• means responsive to said first, second, and third outputs for producing an output signal representative of the concentration of said individual component in said multi-component system, said output signal having a value that is proportional to:
• ##EQU17##

Apparatus for measuring the concentration of individual components of a multi-component mixture, comprising:

• sealed housing means for defining a volume separate from that of said multi-component mixture, said housing means having first and second windows therein;
• means in said housing means for producing a broadband electromagnetic radiation beam that includes a selected strongly absorbing band for one of said components in said mixture, said beam of radiation also including a weakly absorbing region for said one of said components in said mixture;
• chopping means for dividing said broadband beam into at least first, second and third electromagnetic radiation pulses, wherein said first and third radiation pulses are at a wavelength in said weakly absorbing region, said second pulse being at a wavelength in said strongly absorbing band;
• said first, second and third radiation pulses being temporally related according to a selected order;
• means for directing said first, second, and third pulses in a common path through said first window, across said multi-component mixture and through said second window back into said housing;
• said sealed housing means being effective to generate a fourth unchopped background electromagnetic radiation pulse;
• an electromagnetic radiation sensor having a linear response with respect to sensed radiation intensity, said sensor being responsive to said first, second, third and fourth radiation pulses for producing first, second, third and fourth sensor pulses representing said respective first, second, third and fourth radiation pulses, said sensor pulses having a respective total value over time proportional to the respective amount N1, N2, N3 and N4 of each said respective first, second, third and fourth radiation pulses that is transmitted back into said housing means onto said sensor;
• and
• means responsive to said sensor pulses for calculating the value of the difference between said amount N2 minus said amount N4, and dividing said difference by the value of said N1 and N3 amounts interpolated to the time interval over which said amount N2 is sensed, said dividing being done after subtracting from said value of said N1 and N3 amounts said N4 amount.

A method of measuring the concentration of water vapor that forms a component of a multi-component system, comprising the steps of:

• generating a beam of electromagnetic radiation in the form of separate pulses including first, second and third pulses, wherein said first and second pulses are in a wavelength band selected for weak absorption by said water vapor component, wherein said third pulse is in a wavelength region selected for strong absorption by said water vapor component, and wherein said wavelength bands and regions are within a range of from 1 to 3.8 microns, said first, second and third pulses being in a selected temporal order;
• directing said pulses across a sample of said system to variably absorb said third pulse according to the concentration of said water vapor component in said sample;
• and
• using an indium arsenide detector to linearly with respect to radiation intensity at said strong and weak absorption wavelengths and successively convert said first, second and third pulses to separate output pulses to indicate the concentration of said water vapor component in said sample.

A method of measuring the concentration of an individual component of a multi-component system, comprising the steps of:

• generating a beam of electromagnetic radiation in the form of separate pulses including first, second, third and fourth pulses, wherein said first and third pulses are in a wavelength region selected for weak absorption by said component and wherein said third pulse is in a wavelength band selected for strong absorption by said component, said fourth pulse is nominally of zero amplitude, said beam including background electromagnetic radiation super-imposed on said first, second, third and fourth pulses to vary the amplitude of all such pulses by the intensity of said background electromagnetic radiation, said pulses being temporally related such that one of said first and second pulses temporally precedes said third pulse and the other of said first and second pulses temporally follows said third pulse, the amounts of said temporal preceding and following being equal;
• directing said first, second, third and fourth pulses across a sample of said system to variably absorb said third pulse according to the concentration of said component in said sample;
• using an indium arsenide sensor to successively convert said first, second, third and fourth pulses to separate output pulses, wherein said output pulses have respective total values N1, N2, N3 and N4 over time and proportional to said respective first, second, third and fourth pulses that are transmitted back into said housing onto said sensor;
• and
• calculating the value of:
• ##EQU19## to indicate the concentration of said component in said sample.

A method of indicating the water vapor content of a sample, comprising the steps of:

• generating a beam of infrared energy in the form of separate pulses including first, second, and third infrared energy pulses, wherein said first and second pulses are at a wavelength in a weak water vapor absorption region centered at about 2.5 microns and said third pulse is at a wavelength in a strong water vapor absorption band centered at about 2.6 microns;
• temporally relating said first, second, and third pulses such that one of said first and second pulses temporally precedes said third pulse and the other of said first and second pulses temporally follows said third pulse;
• directing said infrared energy pulses across said sample to variably absorb said third pulse according to the water vapor content of said sample;
• using an indium arsenide sensor to successively convert said temporally preceding, middle and following pulses to separate pulses A, B and C respectively wherein said pulses A, B and C have total values NA, NB, and NC over time proportional to the amplitude of each said respective pulses A, B and C that is transmitted back into said housing onto said sensor;
• and
• calculating the value of:
• ##EQU20## to indicate the water vapor content of said sample, where KA and KC sum to 1.00 and are chosen to yield a time-weighted average of said values NA and NC that is applicable at the time of said pulse B.