Back to results
US 4,866,200 AGranted
Process for the coproduction of aromatic carboxylates and alkyl iodides
AssigneeEastman Kodak Company
InventorsMark Rule, Thomas H. Larkins, Jr., Donald W. Lane, Guy R. Steinmetz
Life of this patent
Estimating the term…
Abstract
Disclosed is a process for the co-production of aromatic carboxylic esters and alkyl iodides by the carbonylation of aromatic iodides in the presence of an alkanol and a palladium catalyst.
Claims10
A process comprising
- (A) co-production of an aromatic carboxylic ester and an alkyl iodide by carbonylating an aromatic iodide in the presence of carbon monoxide, an alkanol and a catalytic amount of a palladium catalyst under aromatic carboxylic ester and alkyl iodide-forming conditions of temperature and pressure wherein there are no significant amounts of basic materials which preferentially combine with hydrogen iodide and interfere with the formation of an alkyl iodide, and
- (B) recovering the alkyl iodide.
A process comprising
- (A) co-production of an aromatic dicarboxylate selected from the group consisting of a benzenedicarboxylate and a naphthalene dicarboxylate and methyl iodide by carbonylating a diiodobenzene or a diiodonaphthalene in the presence of carbon monoxide, methanol, an organic solvent and a catalytic amount of a palladium catalyst at a temperature of about 150.degree. to 200.degree. C. and a pressure of about 300 to 1,000 psig wherein there are no significant amounts of basic materials which preferentially combine with hydrogen iodide and interfere with the formation of an alkyl iodide, and
- (B) recovering the methyl iodide.
A process comprising
- (A) co-production of dimethyl 2,6-naphthalenedicarboxylate and methyl iodide by carbonylating 2,6-diiodonaphthalene in the presence of carbon monoxide, methanol, and organic co-solvent and a catalytic amount of palladium at a temperature of about 175.degree. C. and a pressure of about 1000 psig wherein there are no significant amounts of basic materials which preferentially combine with hydrogen iodide and interfere with the formation of an alkyl iodide, and
- (B) recovering the methyl iodide.
Dependencies are inferred from the claim text.