Method for making cationically polymerizable aromatic polypropenyl ethers
AssigneeGeneral Electric Company
InventorsJames V. Crivello, David A. Conlon
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Abstract
A method is provided for making cationically polymerizable aromatic polypropenylethers and to the aromatic polypropenylethers made thereby. Aromatic polyalkylene glycol prepared from the corresponding polyphenol is reacted with an allylhalide to produce aromatic polyallylether which is thereafter isoemrized to the corresponding cationically polymerizable aromatic polypropenylether.
Claims4
A method for making cationically polymerizable polypropenylethers of the formula ##STR15## which comprises, (i) effecting reaction between a polyfunctional aromatic ester of the formula ##STR16## and an allylether of an alkylene glycol of the formula,
- (R.sup.5).sub.2 CR.sup.4 --CH(R.sup.3)OR.sup.2 OH,
- (ii) heating the aromatic polyallylether of (i) in the presence of an isomerization catalyst selected from the class consisting of metallic palladium, platinum or rhodium on carbon, silicia, or alumina, tris(triphenylphosphone) ruthenium dichloride, [Ir(cyclo-octa-1,5-diene)(PCH.sub.3 Ph.sub.2).sub.2 ].sup.+ PF.sub.6.sup.-, PdCl.sub.2 (PhCN).sub.2, Fe(CO).sub.5, RhCl(PPh.sub.3).sub.3, and H.sub.2 Ru(PPh.sub.3).sub.4,
- where R.sup.1 is a polyvalent aromatic radical, R.sup.2 is a C.sub.(1-8) alkylene radical, R.sup.3, R.sup.4 and R.sup.5 are the same or different monovalent radials selected from hydrogen, halogen and C.sub.(1-8) alkyl radicals, R.sup.6 is a C.sub.(1-8) alkyl radical, n is an integer equal to 2 and 10 inclusive and m is an integer having a value of from 2 to 4 inclusive.
A method for making cationically polymerizable polypropenylethers of the formula,
- R.sup.1 [OR.sup.2 OCR.sup.3 .dbd.CR.sup.4 --CH(R.sup.5).sub.2 ].sub.n
- which comprises,
- (A) effecting reaction between an aromatic polyglycol of the formula
- R.sup.1 [OR.sup.2 OH].sub.n
- and an allylhalide in the presence of an acid acceptor to produce an aromatic polyallylether of the formula.
- R.sup.1 [OR.sup.2 OCHR.sup.3 --CR.sup.4 .dbd.C(R.sup.5).sub.2 ].sub.n
- (B) heating the aromatic polyallylether in the presence of an effective amount of RuCl.sub.2 (PPh.sub.3).sub.3 to produce the desired cationically polymerizable polypropenylether,
- where R.sup.1 is a polyvalent aromatic radical, R.sup.2 is a C.sub.(1-8) alkylene radical, R.sup.3, R.sup.4 and R.sup.5 are the same or different monovalent radicals selected from hydrogen, halogen and C.sub.(1-8) alkyl radicals and n is an integer equal to 2 to 10 inclusive.
Dependencies are inferred from the claim text.